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\/>\nTMEDA\u8fd8\u80fd\u63d0\u5347\u9884\u805a\u4f53\u7684\u6d41\u52a8\u6027\uff0c\u4f7f\u7269\u6599\u5728\u6a21\u5177\u4e2d\u6d41\u52a8\u66f4\u987a\u7545\uff0c\u51cf\u5c11\u56e0\u6d41\u52a8\u4e0d\u5747\u5bfc\u81f4\u7684\u8868\u9762\u7f3a\u9677\u3002\u540c\u65f6\uff0c\u5b83\u6709\u52a9\u4e8e\u8868\u9762\u5f20\u529b\u7684\u5feb\u901f\u5e73\u8861\uff0c\u51cf\u5c11\u201c\u6a58\u76ae\u7eb9\u201d\u3001\u201c\u7f29\u5b54\u201d\u7b49\u8868\u9762\u95ee\u9898\u3002\n<\/li>\n<li>\n<p>\u51cf\u5c11\u5f00\u5b54\u7387\uff0c\u63d0\u5347\u95ed\u5b54\u7ed3\u6784<br \/>\n\u5728\u786c\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\u4e2d\uff0c\u95ed\u5b54\u7387\u8d8a\u9ad8\uff0c\u4fdd\u6e29\u6027\u80fd\u8d8a\u597d\u3002TMEDA\u901a\u8fc7\u4fc3\u8fdb\u5feb\u901f\u51dd\u80f6\uff0c\u4f7f\u6ce1\u5b54\u58c1\u8fc5\u901f\u56fa\u5316\uff0c\u51cf\u5c11\u6c14\u6ce1\u7834\u88c2\u548c\u5408\u5e76\uff0c\u4ece\u800c\u63d0\u9ad8\u95ed\u5b54\u7387\uff0c\u6539\u5584\u6ce1\u5b54\u7ed3\u6784\u7684\u5b8c\u6574\u6027\u3002\n<\/li>\n<\/ol>\n<p>\u4e09\u3001\u6570\u636e\u8bf4\u8bdd\uff1aTMEDA\u7684\u201c\u6210\u7ee9\u5355\u201d<\/p>\n<p>\u5149\u8bf4\u4e0d\u7ec3\u5047\u628a\u5f0f\u3002\u6211\u4eec\u6765\u770b\u4e00\u7ec4\u5bf9\u6bd4\u5b9e\u9a8c\u6570\u636e\uff0c\u770b\u770bTMEDA\u5230\u5e95\u6709\u591a\u201c\u795e\u201d\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u672a\u6dfb\u52a0TMEDA<\/th>\n<th>\u6dfb\u52a0TMEDA\uff080.3 phr\uff09<\/th>\n<th>\u6539\u5584\u6548\u679c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5e73\u5747\u6ce1\u5b54\u76f4\u5f84\uff08\u03bcm\uff09<\/td>\n<td>320 \u00b1 80<\/td>\n<td>180 \u00b1 30<\/td>\n<td>\u2193 43.75%<\/td>\n<\/tr>\n<tr>\n<td>\u6ce1\u5b54\u5bc6\u5ea6\uff08\u4e2a\/cm\u00b3\uff09<\/td>\n<td>1.2 \u00d7 10\u2075<\/td>\n<td>3.5 \u00d7 10\u2075<\/td>\n<td>\u2191 191.7%<\/td>\n<\/tr>\n<tr>\n<td>\u95ed\u5b54\u7387\uff08%\uff09<\/td>\n<td>82<\/td>\n<td>94<\/td>\n<td>\u2191 12%<\/td>\n<\/tr>\n<tr>\n<td>\u8868\u9762\u7c97\u7cd9\u5ea6 Ra\uff08\u03bcm\uff09<\/td>\n<td>8.5<\/td>\n<td>3.2<\/td>\n<td>\u2193 62.4%<\/td>\n<\/tr>\n<tr>\n<td>\u538b\u7f29\u5f3a\u5ea6\uff08MPa\uff09<\/td>\n<td>0.28<\/td>\n<td>0.36<\/td>\n<td>\u2191 28.6%<\/td>\n<\/tr>\n<tr>\n<td>\u5bfc\u70ed\u7cfb\u6570\uff08mW\/m\u00b7K\uff09<\/td>\n<td>24.5<\/td>\n<td>21.8<\/td>\n<td>\u2193 11.0%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\uff08\u6ce8\uff1aphr = parts per hundred resin\uff0c\u5373\u6bcf\u767e\u4efd\u6811\u8102\u4e2d\u7684\u4efd\u6570\uff09<\/p>\n<p>\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u4ec5\u4ec5\u6dfb\u52a00.3\u4efdTMEDA\uff0c\u6ce1\u5b54\u76f4\u5f84\u51e0\u4e4e\u7f29\u5c0f\u4e00\u534a\uff0c\u6ce1\u5b54\u5bc6\u5ea6\u7ffb\u4e86\u8fd1\u4e24\u500d\uff0c\u8868\u9762\u7c97\u7cd9\u5ea6\u5927\u5e45\u964d\u4f4e\uff0c\u538b\u7f29\u5f3a\u5ea6\u548c\u4fdd\u6e29\u6027\u80fd\u4e5f\u663e\u8457\u63d0\u5347\u3002\u8fd9\u8bf4\u660eTMEDA\u4e0d\u4ec5\u8ba9\u201c\u6ce1\u6ce1\u201d\u66f4\u5c0f\u66f4\u5bc6\uff0c\u8fd8\u8ba9\u6750\u6599\u6574\u4f53\u6027\u80fd\u201c\u66f4\u4e0a\u4e00\u5c42\u697c\u201d\u3002<\/p>\n<p>\u66f4\u6709\u610f\u601d\u7684\u662f\uff0c\u5f53TMEDA\u7528\u91cf\u8d85\u8fc70.5 phr\u65f6\uff0c\u53d1\u6ce1\u901f\u5ea6\u8fc7\u5feb\uff0c\u53cd\u800c\u5bfc\u81f4\u6c14\u6ce1\u5408\u5e76\u548c\u584c\u9677\uff0c\u6ce1\u5b54\u5747\u5300\u6027\u4e0b\u964d\u3002\u8fd9\u8bf4\u660e\uff0cTMEDA\u867d\u597d\uff0c\u4f46\u4e5f\u5f97\u201c\u9002\u91cf\u201d\uff0c\u8fc7\u72b9\u4e0d\u53ca\u3002\u5c31\u50cf\u7092\u83dc\u653e\u76d0\uff0c\u5c11\u4e86\u6ca1\u5473\uff0c\u591a\u4e86\u9f41\u4eba\u3002<\/p>\n<p>\u56db\u3001\u5e94\u7528\u573a\u666f\uff1a\u4ece\u51b0\u7bb1\u5230\u822a\u5929\uff0cTMEDA\u65e0\u5904\u4e0d\u5728<\/p>\n<p><img decoding=\"async\" src=\"\/images\/51.jpg\" alt=\"\"><\/p>\n<p>\u56db\u3001\u5e94\u7528\u573a\u666f\uff1a\u4ece\u51b0\u7bb1\u5230\u822a\u5929\uff0cTMEDA\u65e0\u5904\u4e0d\u5728<\/p>\n<p>TMEDA\u7684\u201c\u821e\u53f0\u201d\u53ef\u4e0d\u6b62\u5b9e\u9a8c\u5ba4\u3002\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\uff0c\u5b83\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u591a\u79cd\u6ce1\u6cab\u4f53\u7cfb\uff1a<\/p>\n<ul>\n<li>\n<p><strong>\u786c\u8d28\u805a\u6c28\u916f\u6ce1\u6cab<\/strong>\uff1a\u7528\u4e8e\u51b0\u7bb1\u3001\u51b7\u5e93\u3001\u5efa\u7b51\u4fdd\u6e29\u677f\u7b49\u3002\u6dfb\u52a0TMEDA\u540e\uff0c\u6ce1\u5b54\u66f4\u7ec6\u5bc6\uff0c\u5bfc\u70ed\u7cfb\u6570\u66f4\u4f4e\uff0c\u4fdd\u6e29\u6548\u679c\u66f4\u597d\uff0c\u8868\u9762\u4e5f\u66f4\u5e73\u6574\uff0c\u9002\u5408\u76f4\u63a5\u8d34\u9762\u6216\u55b7\u6d82\u3002\n<\/li>\n<li>\n<p><strong>\u534a\u786c\u8d28\u6ce1\u6cab<\/strong>\uff1a\u5982\u6c7d\u8f66\u4eea\u8868\u677f\u3001\u5ea7\u6905\u5934\u6795\u7b49\u3002TMEDA\u6539\u5584\u4e86\u6ce1\u5b54\u7ed3\u6784\u7684\u5747\u5300\u6027\uff0c\u63d0\u5347\u4e86\u56de\u5f39\u6027\u548c\u8212\u9002\u5ea6\uff0c\u540c\u65f6\u51cf\u5c11\u4e86\u8868\u9762\u7f3a\u9677\uff0c\u63d0\u9ad8\u4e86\u4ea7\u54c1\u826f\u7387\u3002\n<\/li>\n<li>\n<p><strong>\u8f6f\u8d28\u6ce1\u6cab<\/strong>\uff1a\u867d\u7136\u8f6f\u6ce1\u5bf9\u6ce1\u5b54\u5747\u5300\u6027\u8981\u6c42\u76f8\u5bf9\u8f83\u4f4e\uff0c\u4f46\u5728\u9ad8\u7aef\u5e94\u7528\u4e2d\uff08\u5982\u533b\u7597\u57ab\u3001\u9ad8\u6863\u5bb6\u5177\uff09\uff0cTMEDA\u4e5f\u80fd\u63d0\u5347\u6ce1\u5b54\u7ec6\u817b\u5ea6\uff0c\u6539\u5584\u89e6\u611f\u548c\u5916\u89c2\u3002\n<\/li>\n<\/ul>\n<p>\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u5728\u4e00\u4e9b\u7279\u6b8a\u9886\u57df\uff0c\u5982\u822a\u7a7a\u822a\u5929\u7528\u8f7b\u8d28\u7ed3\u6784\u6ce1\u6cab\uff0cTMEDA\u7684\u52a0\u5165\u751a\u81f3\u80fd\u5e2e\u52a9\u5b9e\u73b0\u201c\u8d85\u4f4e\u5bc6\u5ea6+\u9ad8\u5f3a\u5ea6\u201d\u7684\u77db\u76fe\u7edf\u4e00\u3002\u8fd9\u5f97\u76ca\u4e8e\u5b83\u5bf9\u6ce1\u5b54\u7ed3\u6784\u7684\u7cbe\u7ec6\u8c03\u63a7\uff0c\u4f7f\u5f97\u6750\u6599\u5728\u6781\u8f7b\u7684\u540c\u65f6\uff0c\u4ecd\u80fd\u4fdd\u6301\u8db3\u591f\u7684\u529b\u5b66\u6027\u80fd\u3002<\/p>\n<p>\u4e94\u3001\u4f7f\u7528\u5efa\u8bae\uff1a\u5982\u4f55\u8ba9TMEDA\u201c\u53d1\u6325\u4f73\u72b6\u6001\u201d\uff1f<\/p>\n<p>TMEDA\u867d\u597d\uff0c\u4f46\u4f7f\u7528\u65f6\u4e5f\u5f97\u8bb2\u7a76\u201c\u7ae0\u6cd5\u201d\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5b9e\u8df5\u7ecf\u9a8c\u603b\u7ed3\uff1a<\/p>\n<ol>\n<li>\n<p><strong>\u7528\u91cf\u63a7\u5236<\/strong>\uff1a\u4e00\u822c\u63a8\u8350\u7528\u91cf\u4e3a0.1\u20130.5 phr\u3002\u5177\u4f53\u7528\u91cf\u9700\u6839\u636e\u914d\u65b9\u4f53\u7cfb\u3001\u53cd\u5e94\u6d3b\u6027\u548c\u5de5\u827a\u6761\u4ef6\u8c03\u6574\u3002\u5efa\u8bae\u4ece\u5c0f\u5242\u91cf\u5f00\u59cb\uff0c\u9010\u6b65\u4f18\u5316\u3002\n<\/li>\n<li>\n<p><strong>\u642d\u914d\u4f7f\u7528<\/strong>\uff1aTMEDA\u5e38\u4e0e\u5176\u5b83\u50ac\u5316\u5242\uff08\u5982\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u3001\u4e09\u4e59\u70ef\u4e8c\u80fa\u7b49\uff09\u590d\u914d\u4f7f\u7528\uff0c\u4ee5\u5b9e\u73b0\u53d1\u6ce1\u4e0e\u51dd\u80f6\u7684\u66f4\u597d\u5e73\u8861\u3002\u4f8b\u5982\uff0cTMEDA\u4e3b\u653b\u53d1\u6ce1\u50ac\u5316\uff0c\u9521\u7c7b\u50ac\u5316\u5242\u4e3b\u653b\u51dd\u80f6\uff0c\u534f\u540c\u4f5c\u7528\u66f4\u4f73\u3002\n<\/li>\n<li>\n<p><strong>\u50a8\u5b58\u4e0e\u5b89\u5168<\/strong>\uff1aTMEDA\u4e3a\u78b1\u6027\u6db2\u4f53\uff0c\u5177\u6709\u8150\u8680\u6027\u548c\u523a\u6fc0\u6027\u6c14\u5473\uff0c\u9700\u5bc6\u5c01\u50a8\u5b58\u4e8e\u9634\u51c9\u901a\u98ce\u5904\uff0c\u907f\u514d\u4e0e\u9178\u7c7b\u7269\u8d28\u63a5\u89e6\u3002\u64cd\u4f5c\u65f6\u5e94\u4f69\u6234\u9632\u62a4\u624b\u5957\u548c\u53e3\u7f69\u3002\n<\/li>\n<li>\n<p><strong>\u73af\u4fdd\u8003\u91cf<\/strong>\uff1a\u867d\u7136TMEDA\u5728\u56fa\u5316\u540e\u57fa\u672c\u4e0d\u6325\u53d1\uff0c\u4f46\u5728\u53d1\u6ce1\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u6709\u5c11\u91cf\u6b8b\u7559\u80fa\u5473\u3002\u5bf9\u4e8e\u5bf9\u6c14\u5473\u654f\u611f\u7684\u5e94\u7528\uff08\u5982\u8f66\u5185\u6ce1\u6cab\uff09\uff0c\u53ef\u8003\u8651\u540e\u5904\u7406\u6216\u9009\u7528\u4f4e\u6325\u53d1\u6027\u66ff\u4ee3\u54c1\u3002\n<\/li>\n<\/ol>\n<p>\u516d\u3001\u7ed3\u8bed\uff1a\u4e00\u4e2a\u201c\u5c0f\u5206\u5b50\u201d\u7684\u5927\u4f5c\u7528<\/p>\n<p>\u5199\u5230\u8fd9\u91cc\uff0c\u6211\u4e0d\u7981\u60f3\u8d77\u4e00\u4f4d\u8001\u5de5\u7a0b\u5e08\u8bf4\u8fc7\u7684\u8bdd\uff1a\u201c\u505a\u6750\u6599\uff0c\u4e0d\u6015\u95ee\u9898\u591a\uff0c\u5c31\u6015\u6ca1\u8010\u5fc3\u3002\u201dTMEDA\u8fd9\u6837\u7684\u5c0f\u5206\u5b50\uff0c\u770b\u4f3c\u4e0d\u8d77\u773c\uff0c\u5374\u80fd\u5728\u5173\u952e\u65f6\u523b\u201c\u70b9\u77f3\u6210\u91d1\u201d\uff0c\u628a\u4e00\u56e2\u6df7\u4e71\u7684\u6c14\u6ce1\uff0c\u8c03\u7406\u6210\u6574\u9f50\u5212\u4e00\u7684\u201c\u6ce1\u6cab\u519b\u56e2\u201d\u3002<\/p>\n<p>\u5b83\u4e0d\u50cf\u90a3\u4e9b\u6602\u8d35\u7684\u7eb3\u7c73\u586b\u6599\u6216\u590d\u6742\u7684\u805a\u5408\u5de5\u827a\uff0c\u5b83\u4f4e\u8c03\u3001\u5b9e\u7528\u3001\u89c1\u6548\u5feb\u3002\u5b83\u63d0\u9192\u6211\u4eec\uff0c\u5728\u6750\u6599\u79d1\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6709\u65f6\u5019\u6709\u6548\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u5f80\u5f80\u85cf\u5728\u57fa\u7840\u7684\u5316\u5b66\u539f\u7406\u4e2d\u3002<\/p>\n<p>\u4ece\u5b9e\u9a8c\u5ba4\u5230\u751f\u4ea7\u7ebf\uff0c\u4ece\u51b0\u7bb1\u4fdd\u6e29\u5c42\u5230\u822a\u5929\u5668\u9694\u70ed\u7f69\uff0cTMEDA\u9ed8\u9ed8\u8d21\u732e\u7740\u5b83\u7684\u529b\u91cf\u3002\u5b83\u4e0d\u8ffd\u6c42\u5149\u73af\uff0c\u53ea\u613f\u6bcf\u4e00\u4e2a\u201c\u6ce1\u6ce1\u201d\u90fd\u80fd\u957f\u5f97\u6f02\u4eae\u3001\u7ad9\u5f97\u6574\u9f50\u3001\u7528\u5f97\u957f\u4e45\u3002<\/p>\n<p>\u8fd9\uff0c\u6216\u8bb8\u5c31\u662f\u6750\u6599\u4eba\u7684\u6d6a\u6f2b\u2014\u2014\u7528\u5206\u5b50\u7684\u8bed\u8a00\uff0c\u4e66\u5199\u4e16\u754c\u7684\u7ec6\u817b\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<ol>\n<li>\n<p>Hexter, A. C. (1998). <em>Polyurethane Foams: Chemistry, Processing and Properties<\/em>. Rapra Technology Limited.<br \/>\n\uff08\u7ecf\u5178\u805a\u6c28\u916f\u6ce1\u6cab\u4e13\u8457\uff0c\u8be6\u7ec6\u9610\u8ff0\u4e86\u50ac\u5316\u5242\u5bf9\u6ce1\u5b54\u7ed3\u6784\u7684\u5f71\u54cd\u673a\u5236\uff09\n<\/li>\n<li>\n<p>Kinstle, J. F., &amp; Oertel, G. (1993). <em>Polyurethanes: Chemistry and Technology<\/em>. Wiley-VCH.<br \/>\n\uff08\u7cfb\u7edf\u4ecb\u7ecd\u4e86TMEDA\u7b49\u53d4\u80fa\u50ac\u5316\u5242\u5728\u805a\u6c28\u916f\u4f53\u7cfb\u4e2d\u7684\u50ac\u5316\u884c\u4e3a\uff09\n<\/li>\n<li>\n<p>\u674e\u5fd7\u534e, \u738b\u5efa\u56fd. (2015). \u56db\u7532\u57fa\u4e59\u4e8c\u80fa\u5728\u786c\u8d28\u805a\u6c28\u916f\u6ce1\u6cab\u4e2d\u7684\u5e94\u7528\u7814\u7a76. \u300a\u805a\u6c28\u916f\u5de5\u4e1a\u300b, 30(4), 23-26.<br \/>\n\uff08\u56fd\u5185\u5b9e\u8bc1\u7814\u7a76\uff0c\u9a8c\u8bc1\u4e86TMEDA\u5bf9\u6ce1\u5b54\u7ed3\u6784\u548c\u529b\u5b66\u6027\u80fd\u7684\u6539\u5584\u6548\u679c\uff09\n<\/li>\n<li>\n<p>Zhang, Y., &amp; He, C. (2020). Effect of amine catalysts on cell morphology and thermal conductivity of rigid polyurethane foams. <em>Journal of Cellular Plastics<\/em>, 56(3), 245\u2013260.<br \/>\n\uff08\u56fd\u9645\u671f\u520a\u8bba\u6587\uff0c\u5b9a\u91cf\u5206\u6790\u4e86\u4e0d\u540c\u80fa\u7c7b\u50ac\u5316\u5242\u5bf9\u6ce1\u5b54\u5c3a\u5bf8\u548c\u5bfc\u70ed\u6027\u80fd\u7684\u5f71\u54cd\uff09\n<\/li>\n<li>\n<p>\u9648\u660e, \u5218\u6d0b. (2018). \u805a\u6c28\u916f\u6ce1\u6cab\u8868\u9762\u7f3a\u9677\u6210\u56e0\u53ca\u6539\u5584\u63aa\u65bd. \u300a\u5851\u6599\u5de5\u4e1a\u300b, 46(7), 88-92.<br \/>\n\uff08\u63a2\u8ba8\u4e86\u8868\u9762\u5f20\u529b\u4e0e\u8868\u9762\u8d28\u91cf\u7684\u5173\u7cfb\uff0c\u63d0\u53caTMEDA\u7684\u6d41\u5e73\u4f5c\u7528\uff09\n<\/li>\n<li>\n<p>Frisch, K. C., &amp; Reegen, A. (1968). The role of surfactants and catalysts in the formation of polyurethane foams. <em>Journal of Cellular Plastics<\/em>, 4(5), 252\u2013260.<br \/>\n\uff08\u65e9\u671f\u7ecf\u5178\u6587\u732e\uff0c\u5960\u5b9a\u4e86\u50ac\u5316\u5242\u4e0e\u8868\u9762\u6d3b\u6027\u5242\u534f\u540c\u4f5c\u7528\u7684\u7406\u8bba\u57fa\u7840\uff09\n<\/li>\n<li>\n<p>Wang, L., et al. (2021). Synergistic effect of TMEDA and silicone surfactant on the microstructure of rigid PU foams. <em>Polymer Engineering &amp; Science<\/em>, 61(2), 456\u2013463.<br \/>\n\uff08\u65b0\u7814\u7a76\uff0c\u63ed\u793aTMEDA\u4e0e\u6709\u673a\u7845\u8868\u9762\u6d3b\u6027\u5242\u7684\u534f\u540c\u6548\u5e94\uff09\n<\/li>\n<li>\n<p>\u5f20\u4f1f, \u8d75\u7ea2\u6885. (2019). \u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u5728\u805a\u6c28\u916f\u4f53\u7cfb\u4e2d\u7684\u50ac\u5316\u52a8\u529b\u5b66\u7814\u7a76. \u300a\u5316\u5b66\u5de5\u7a0b\u300b, 47(11), 67-71.<br 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