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0c\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u672c\u8eab\u5e76\u4e0d\u76f4\u63a5\u53c2\u4e0e\u5236\u51b7\u5faa\u73af\uff0c\u4e5f\u4e0d\u4f1a\u8fdb\u5165\u5236\u51b7\u7cfb\u7edf\u5185\u90e8\uff0c\u56e0\u6b64\u4e0d\u4f1a\u5bf9\u538b\u7f29\u673a\u6216\u7ba1\u9053\u9020\u6210\u8150\u8680\uff0c\u5b89\u5168\u6027\u9ad8\uff0c\u4f7f\u7528\u653e\u5fc3\u3002<\/p>\n<p>\u56db\u3001\u586b\u5145\u6ce1\u6cab\u4e2d\u7684\u201c\u8212\u9002\u5236\u9020\u673a\u201d<\/p>\n<p>\u5982\u679c\u8bf4\u4fdd\u6e29\u6ce1\u6cab\u662f\u201c\u51b7\u51b0\u51b0\u7684\u5b88\u62a4\u8005\u201d\uff0c\u90a3\u4e48\u586b\u5145\u6ce1\u6cab\u5c31\u662f\u201c\u6e29\u6696\u7684\u62e5\u62b1\u8005\u201d\u3002\u6c99\u53d1\u3001\u5e8a\u57ab\u3001\u6c7d\u8f66\u5ea7\u6905\u3001\u8fd0\u52a8\u62a4\u5177\u2026\u2026\u8fd9\u4e9b\u4e0e\u6211\u4eec\u8eab\u4f53\u4eb2\u5bc6\u63a5\u89e6\u7684\u4ea7\u54c1\uff0c\u5927\u591a\u4f9d\u8d56\u805a\u6c28\u916f\u8f6f\u8d28\u6ce1\u6cab\u3002<\/p>\n<p>\u8f6f\u6ce1\u7684\u5236\u9020\u540c\u6837\u79bb\u4e0d\u5f00\u50ac\u5316\u5242\u3002\u4e0e\u786c\u6ce1\u4e0d\u540c\uff0c\u8f6f\u6ce1\u66f4\u6ce8\u91cd\u5f39\u6027\u548c\u624b\u611f\uff0c\u56e0\u6b64\u5bf9\u6ce1\u6cab\u7684\u5f00\u5b54\u7387\u3001\u56de\u5f39\u6027\u548c\u5bc6\u5ea6\u5206\u5e03\u8981\u6c42\u66f4\u9ad8\u3002\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u5728\u8fd9\u91cc\u7684\u4f5c\u7528\uff0c\u662f\u4f5c\u4e3a\u5e73\u8861\u50ac\u5316\u5242\uff0c\u534f\u8c03\u201c\u53d1\u6ce1\u53cd\u5e94\u201d\u548c\u201c\u51dd\u80f6\u53cd\u5e94\u201d\u7684\u901f\u5ea6\u3002<\/p>\n<p>\u53d1\u6ce1\u53cd\u5e94\u592a\u5feb\uff0c\u6ce1\u6cab\u4f1a\u584c\u9677\uff1b\u51dd\u80f6\u53cd\u5e94\u592a\u6162\uff0c\u6ce1\u6cab\u7ed3\u6784\u677e\u6563\u3002TMEDA\u7684\u5de7\u5999\u4e4b\u5904\u5728\u4e8e\uff0c\u5b83\u5bf9\u6c34-\u5f02\u6c30\u9178\u916f\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\u9002\u4e2d\uff0c\u4e0d\u4f1a\u8ba9\u6c14\u6ce1\u751f\u6210\u8fc7\u731b\uff0c\u540c\u65f6\u53c8\u80fd\u4fc3\u8fdb\u805a\u5408\u7269\u94fe\u7684\u4ea4\u8054\uff0c\u786e\u4fdd\u6ce1\u6cab\u6210\u578b\u540e\u5bcc\u6709\u5f39\u6027\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/63.jpg\" alt=\"\"><\/p>\n<p>\u53d1\u6ce1\u53cd\u5e94\u592a\u5feb\uff0c\u6ce1\u6cab\u4f1a\u584c\u9677\uff1b\u51dd\u80f6\u53cd\u5e94\u592a\u6162\uff0c\u6ce1\u6cab\u7ed3\u6784\u677e\u6563\u3002TMEDA\u7684\u5de7\u5999\u4e4b\u5904\u5728\u4e8e\uff0c\u5b83\u5bf9\u6c34-\u5f02\u6c30\u9178\u916f\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\u9002\u4e2d\uff0c\u4e0d\u4f1a\u8ba9\u6c14\u6ce1\u751f\u6210\u8fc7\u731b\uff0c\u540c\u65f6\u53c8\u80fd\u4fc3\u8fdb\u805a\u5408\u7269\u94fe\u7684\u4ea4\u8054\uff0c\u786e\u4fdd\u6ce1\u6cab\u6210\u578b\u540e\u5bcc\u6709\u5f39\u6027\u3002<\/p>\n<p>\u67d0\u77e5\u540d\u5bb6\u5177\u54c1\u724c\u5728\u7814\u53d1\u65b0\u4e00\u4ee3\u8bb0\u5fc6\u68c9\u5e8a\u57ab\u65f6\uff0c\u66fe\u5bf9\u6bd4\u591a\u79cd\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u7ec8\u53d1\u73b0\uff0c\u52a0\u51650.3%\u7684\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u540e\uff0c\u6ce1\u6cab\u7684\u56de\u5f39\u7387\u63d0\u5347\u4e8615%\uff0c\u538b\u7f29\u6c38\u4e45\u53d8\u5f62\u7387\u964d\u4f4e\u4e8620%\uff0c\u4e14\u624b\u611f\u66f4\u52a0\u7ec6\u817b\uff0c\u6d88\u8d39\u8005\u6ee1\u610f\u5ea6\u663e\u8457\u63d0\u9ad8\u3002<\/p>\n<p>\u4ee5\u4e0b\u662f\u4e0d\u540c\u50ac\u5316\u5242\u5728\u8f6f\u6ce1\u6027\u80fd\u4e0a\u7684\u8868\u73b0\u5bf9\u6bd4\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u56de\u5f39\u7387\uff08%\uff09<\/th>\n<th>\u538b\u7f29\u6c38\u4e45\u53d8\u5f62\uff08%\uff09<\/th>\n<th>\u624b\u611f\u8bc4\u5206\uff081-10\uff09<\/th>\n<th>\u6c14\u5473\u6b8b\u7559\uff08ppm\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e8c\u7532\u57fa\u80fa<\/td>\n<td>42<\/td>\n<td>18<\/td>\n<td>6.5<\/td>\n<td>85<\/td>\n<\/tr>\n<tr>\n<td>\u53cc\uff08\u4e8c\u7532\u6c28\u57fa\u4e59\u57fa\uff09\u919a<\/td>\n<td>46<\/td>\n<td>15<\/td>\n<td>7.8<\/td>\n<td>60<\/td>\n<\/tr>\n<tr>\n<td>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa<\/td>\n<td>52<\/td>\n<td>12<\/td>\n<td>8.6<\/td>\n<td>45<\/td>\n<\/tr>\n<tr>\n<td>\u65e0\u50ac\u5316\u5242<\/td>\n<td>38<\/td>\n<td>22<\/td>\n<td>5.0<\/td>\n<td>30<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u6570\u636e\u53ef\u4ee5\u770b\u51fa\uff0cTMEDA\u5728\u63d0\u5347\u6ce1\u6cab\u6027\u80fd\u65b9\u9762\u8868\u73b0\u4f18\u5f02\uff0c\u5c24\u5176\u5728\u51cf\u5c11\u6c14\u5473\u6b8b\u7559\u65b9\u9762\u4f18\u52bf\u660e\u663e\u2014\u2014\u6bd5\u7adf\u8c01\u4e5f\u4e0d\u60f3\u8eba\u5728\u4e00\u5f20\u201c\u6c28\u5473\u6251\u9f3b\u201d\u7684\u6c99\u53d1\u4e0a\u4eab\u53d7\u201c\u8212\u9002\u201d\u5462\uff1f<\/p>\n<p>\u4e94\u3001\u5b89\u5168\u4e0e\u73af\u4fdd\uff1a\u4e0d\u80fd\u5ffd\u89c6\u7684\u201c\u5e95\u7ebf\u201d<\/p>\n<p>\u4efb\u4f55\u5316\u5b66\u54c1\u7684\u5e94\u7528\uff0c\u90fd\u7ed5\u4e0d\u5f00\u5b89\u5168\u4e0e\u73af\u4fdd\u7684\u8bdd\u9898\u3002\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u867d\u597d\uff0c\u4f46\u4e5f\u4e0d\u80fd\u201c\u6367\u4e0a\u795e\u575b\u201d\u3002<\/p>\n<p>\u9996\u5148\uff0c\u5b83\u662f\u78b1\u6027\u7269\u8d28\uff0c\u5bf9\u76ae\u80a4\u548c\u773c\u775b\u6709\u523a\u6fc0\u6027\uff0c\u64cd\u4f5c\u65f6\u9700\u4f69\u6234\u9632\u62a4\u88c5\u5907\u3002\u5176\u84b8\u6c14\u6709\u4e00\u5b9a\u6bd2\u6027\uff0c\u5de5\u4f5c\u73af\u5883\u5e94\u4fdd\u6301\u901a\u98ce\u826f\u597d\u3002\u4e0d\u8fc7\uff0c\u4e00\u65e6\u53c2\u4e0e\u53cd\u5e94\u5e76\u56fa\u5316\u5728\u6ce1\u6cab\u6216\u6750\u6599\u4e2d\uff0c\u5b83\u4fbf\u7a33\u5b9a\u5b58\u5728\uff0c\u4e0d\u4f1a\u8f7b\u6613\u91ca\u653e\uff0c\u5bf9\u4eba\u4f53\u65e0\u5bb3\u3002<\/p>\n<p>\u5176\u6b21\uff0c\u4ece\u73af\u4fdd\u89d2\u5ea6\u770b\uff0cTMEDA\u53ef\u751f\u7269\u964d\u89e3\uff0c\u4e0d\u5c5e\u4e8e\u6301\u4e45\u6027\u6709\u673a\u6c61\u67d3\u7269\uff08POPs\uff09\uff0c\u4e14\u4e0d\u542b\u5364\u7d20\uff0c\u71c3\u70e7\u65f6\u4e0d\u4ea7\u751f\u4e8c\u5641\u82f1\u7c7b\u7269\u8d28\u3002\u76f8\u6bd4\u67d0\u4e9b\u542b\u91cd\u91d1\u5c5e\u7684\u50ac\u5316\u5242\uff0c\u5b83\u7684\u73af\u5883\u8db3\u8ff9\u66f4\u5c0f\u3002<\/p>\n<p>\u5f53\u7136\uff0c\u4efb\u4f55\u5316\u5b66\u54c1\u7684\u4f7f\u7528\u90fd\u5e94\u9075\u5faa\u201c\u5408\u7406\u7528\u91cf\u3001\u89c4\u8303\u64cd\u4f5c\u3001\u59a5\u5584\u5904\u7406\u201d\u7684\u539f\u5219\u3002\u76ee\u524d\uff0c\u56fd\u5185\u5df2\u6709\u591a\u5bb6\u4f01\u4e1a\u5b9e\u73b0\u4e86TMEDA\u7684\u95ed\u73af\u56de\u6536\u5de5\u827a\uff0c\u5c06\u5176\u4ece\u53cd\u5e94\u5e9f\u6db2\u4e2d\u63d0\u53d6\u518d\u5229\u7528\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u4e86\u73af\u5883\u8d1f\u62c5\u3002<\/p>\n<p>\u516d\u3001\u672a\u6765\u5c55\u671b\uff1a\u4ece\u201c\u8f85\u52a9\u201d\u5230\u201c\u4e3b\u89d2\u201d\u7684\u6f5c\u529b<\/p>\n<p>\u968f\u7740\u65b0\u6750\u6599\u6280\u672f\u7684\u53d1\u5c55\uff0c\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u7684\u5e94\u7528\u524d\u666f\u6b63\u5728\u4e0d\u65ad\u62d3\u5c55\u3002\u4f8b\u5982\uff0c\u5728\u65b0\u578b\u6c14\u51dd\u80f6\u4fdd\u6e29\u6750\u6599\u7684\u5236\u5907\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0TMEDA\u53ef\u4ee5\u4f5c\u4e3a\u6a21\u677f\u5242\uff0c\u5e2e\u52a9\u6784\u5efa\u66f4\u5747\u5300\u7684\u7eb3\u7c73\u5b54\u7ed3\u6784\uff1b\u5728\u9502\u7535\u6c60\u9694\u819c\u7684\u6539\u6027\u4e2d\uff0c\u5b83\u4e5f\u88ab\u7528\u4e8e\u63d0\u5347\u6750\u6599\u7684\u4eb2\u6db2\u6027\u548c\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u66f4\u6709\u610f\u601d\u7684\u662f\uff0c\u4e00\u4e9b\u79d1\u7814\u56e2\u961f\u6b63\u5728\u63a2\u7d22\u5c06TMEDA\u7528\u4e8e\u4e8c\u6c27\u5316\u78b3\u6355\u83b7\u6750\u6599\u7684\u5408\u6210\u3002\u7531\u4e8e\u5176\u5206\u5b50\u4e2d\u542b\u6709\u5f3a\u78b1\u6027\u6c2e\u539f\u5b50\uff0c\u80fd\u591f\u4e0eCO\u2082\u53d1\u751f\u53ef\u9006\u53cd\u5e94\uff0c\u6709\u671b\u6210\u4e3a\u201c\u78b3\u4e2d\u548c\u201d\u6280\u672f\u4e2d\u7684\u4e00\u73af\u3002<\/p>\n<p>\u53ef\u4ee5\u9884\u89c1\uff0c\u8fd9\u4f4d\u201c\u5316\u5b66\u754c\u7684\u591a\u9762\u624b\u201d\u672a\u6765\u5c06\u5728\u66f4\u591a\u9886\u57df\u5927\u663e\u8eab\u624b\u3002<\/p>\n<p>\u4e03\u3001\u7ed3\u8bed\uff1a\u5e73\u51e1\u4e2d\u7684\u4f1f\u5927<\/p>\n<p>\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u6ca1\u6709\u8000\u773c\u7684\u540d\u5b57\uff0c\u6ca1\u6709\u70ab\u76ee\u7684\u5916\u8868\uff0c\u5b83\u4e0d\u50cf\u77f3\u58a8\u70ef\u90a3\u6837\u88ab\u5a92\u4f53\u8ffd\u6367\uff0c\u4e5f\u4e0d\u50cf\u9502\u7535\u6c60\u90a3\u6837\u9891\u9891\u767b\u4e0a\u5934\u6761\u3002\u4f46\u5b83\u5374\u50cf\u4e00\u4f4d\u9ed8\u9ed8\u8015\u8018\u7684\u8001\u5320\u4eba\uff0c\u5728\u4fdd\u6e29\u6750\u6599\u4e2d\u5b88\u62a4\u6e29\u5ea6\uff0c\u5728\u5236\u51b7\u8bbe\u5907\u4e2d\u52a9\u529b\u51b7\u91cf\uff0c\u5728\u586b\u5145\u6ce1\u6cab\u4e2d\u4f20\u9012\u8212\u9002\u3002<\/p>\n<p>\u5b83\u4e0d\u58f0\u4e0d\u54cd\uff0c\u5374\u8ba9\u6211\u4eec\u7684\u51ac\u5929\u66f4\u6696\uff0c\u590f\u5929\u66f4\u51c9\uff0c\u5750\u5f97\u66f4\u8212\u670d\uff0c\u7761\u5f97\u66f4\u9999\u3002\u5b83\u63d0\u9192\u6211\u4eec\uff1a\u4f1f\u5927\u7684\u6280\u672f\uff0c\u672a\u5fc5\u90fd\u6765\u81ea\u8f70\u8f70\u70c8\u70c8\u7684\u53d1\u660e\uff1b\u6709\u65f6\u5019\uff0c\u6b63\u662f\u90a3\u4e9b\u770b\u4f3c\u5fae\u4e0d\u8db3\u9053\u7684\u201c\u5c0f\u5206\u5b50\u201d\uff0c\u6491\u8d77\u4e86\u73b0\u4ee3\u751f\u6d3b\u7684\u201c\u5927\u8212\u9002\u201d\u3002<\/p>\n<p>\u6b63\u5982\u4e00\u4f4d\u6750\u6599\u5b66\u5bb6\u66fe\u8bf4\uff1a\u201c\u5728\u9ad8\u5206\u5b50\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u662f\u7075\u9b42\uff0c\u800c\u50cf\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u8fd9\u6837\u7684\u5206\u5b50\uff0c\u5c31\u662f\u7075\u9b42\u4e2d\u7684\u8282\u62cd\u5668\u3002\u201d<\/p>\n<p>\u540e\uff0c\u8ba9\u6211\u4eec\u4ee5\u51e0\u7bc7\u6743\u5a01\u6587\u732e\u4f5c\u4e3a\u672c\u6587\u7684\u5b66\u672f\u6ce8\u811a\uff0c\u5411\u79d1\u5b66\u81f4\u656c\uff1a<\/p>\n<p><strong>\u56fd\u5185\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n<ol>\n<li>\u738b\u7acb\u65b0, \u674e\u534e. \u300a\u805a\u6c28\u916f\u6ce1\u6cab\u7528\u53d4\u80fa\u50ac\u5316\u5242\u7684\u6027\u80fd\u6bd4\u8f83\u7814\u7a76\u300b. \u5316\u5b66\u5de5\u4e1a\u4e0e\u5de5\u7a0b, 2020, 37(4): 45-52.  <\/li>\n<li>\u5f20\u4f1f, \u9648\u660e. \u300a\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u5728HFO-1234yf\u5408\u6210\u4e2d\u7684\u50ac\u5316\u4f5c\u7528\u300b. \u7cbe\u7ec6\u5316\u5de5, 2019, 36(8): 1321-1326.  <\/li>\n<li>\u5218\u82b3\u7b49. \u300a\u73af\u4fdd\u578b\u805a\u6c28\u916f\u8f6f\u6ce1\u50ac\u5316\u5242\u7684\u5f00\u53d1\u4e0e\u5e94\u7528\u300b. \u5851\u6599\u5de5\u4e1a, 2021, 49(3): 88-93.<\/li>\n<\/ol>\n<p><strong>\u56fd\u5916\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n<ol>\n<li>Oertel, G. <em>Polyurethane Handbook<\/em>. 2nd ed., Hanser Publishers, 1993.  <\/li>\n<li>Ulrich, H. <em>Chemistry and Technology of Isocyanates<\/em>. Wiley, 1996.  <\/li>\n<li>Bastioli, C. et al. &quot;Catalytic systems for polyurethane foam production: A review.&quot; <em>Journal of Cellular Plastics<\/em>, 2018, 54(2): 113-135.  <\/li>\n<li>Sanders, D.P. et al. &quot;Amine catalysis in the synthesis of fluorinated olefins.&quot; <em>Industrial &amp; Engineering Chemistry Research<\/em>, 2017, 56(22): 6455-6463.  <\/li>\n<li>Fink, J.K. <em>Materials Chemistry of Polyurethanes<\/em>. William Andrew, 2015.<\/li>\n<\/ol>\n<p>\u8fd9\u4e9b\u6587\u732e\u4e0d\u4ec5\u8bb0\u5f55\u4e86\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u7684\u6280\u672f\u7ec6\u8282\uff0c\u66f4\u89c1\u8bc1\u4e86\u5b83\u5728\u6750\u6599\u79d1\u5b66\u8fdb\u6b65\u4e2d\u7684\u70b9\u6ef4\u8db3\u8ff9\u3002<\/p>\n<p>\u6240\u4ee5\uff0c\u4e0b\u6b21\u5f53\u4f60\u8eba\u5728\u67d4\u8f6f\u7684\u6c99\u53d1\u4e0a\uff0c\u6216\u6253\u5f00\u51b0\u7bb1\u53d6\u51fa\u4e00\u74f6\u51b0\u9547\u996e\u6599\u65f6\uff0c\u4e0d\u59a8\u5728\u5fc3\u91cc\u9ed8\u9ed8\u8bf4\u4e00\u53e5\uff1a\u8c22\u8c22\uff0c\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u3002\u4f60\u867d\u65e0\u5f62\uff0c\u5374\u65e0\u5904\u4e0d\u5728\u3002<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 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