{"id":10320,"date":"2025-06-14T08:15:16","date_gmt":"2025-06-14T00:15:16","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10320"},"modified":"2025-06-14T08:15:16","modified_gmt":"2025-06-14T00:15:16","slug":"%e6%af%94%e8%be%83%e4%b8%8d%e5%90%8c%e6%b0%b4%e6%ba%b6%e6%80%a7%e7%8e%af%e4%bf%9d%e9%87%91%e5%b1%9e%e5%82%ac%e5%8c%96%e5%89%82%e5%9c%a8%e4%b8%8d%e5%90%8c%e4%bd%93%e7%b3%bb%e4%b8%8b%e7%9a%84%e8%a1%a8","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10320","title":{"rendered":"\u6bd4\u8f83\u4e0d\u540c\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u4e0d\u540c\u4f53\u7cfb\u4e0b\u7684\u8868\u73b0"},"content":{"rendered":"<h1>\u4e0d\u540c\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u4e0d\u540c\u4f53\u7cfb\u4e0b\u7684\u8868\u73b0\u6bd4\u8f83\uff1a\u4e00\u573a\u7eff\u8272\u5316\u5b66\u7684\u201c\u53a8\u827a\u5927\u6bd4\u62fc\u201d<\/h1>\n<hr \/>\n<h2>\u5f15\u8a00\uff1a\u50ac\u5316\u5242\uff0c\u4e0d\u53ea\u662f\u53cd\u5e94\u7684\u201c\u52a0\u901f\u5668\u201d\uff0c\u66f4\u662f\u7eff\u8272\u672a\u6765\u7684\u201c\u8c03\u5473\u5e08\u201d<\/h2>\n<p>\u5982\u679c\u4f60\u628a\u5316\u5b66\u53cd\u5e94\u770b\u6210\u4e00\u9053\u83dc\uff0c\u90a3\u50ac\u5316\u5242\u5c31\u662f\u90a3\u4e2a\u51b3\u5b9a\u8fd9\u9053\u83dc\u662f\u7c73\u5176\u6797\u4e09\u661f\u8fd8\u662f\u8def\u8fb9\u644a\u7684\u7075\u9b42\u4eba\u7269\u3002\u800c\u968f\u7740\u5168\u7403\u5bf9\u73af\u4fdd\u95ee\u9898\u7684\u65e5\u76ca\u91cd\u89c6\uff0c\u4f20\u7edf\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u6bd4\u5982\u94af\u3001\u94c2\u3001\u6c5e\u7b49\uff09\u56e0\u4e3a\u6bd2\u6027\u9ad8\u3001\u4ef7\u683c\u8d35\u3001\u96be\u56de\u6536\u7b49\u95ee\u9898\uff0c\u8d8a\u6765\u8d8a\u4e0d\u88ab\u5f85\u89c1\u4e86\u3002\u4e8e\u662f\uff0c\u79d1\u5b66\u5bb6\u4eec\u5f00\u59cb\u5bfb\u627e\u4e00\u79cd\u65e2\u73af\u4fdd\u53c8\u9ad8\u6548\u7684\u66ff\u4ee3\u54c1\u2014\u2014<strong>\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242<\/strong>\u5e94\u8fd0\u800c\u751f\u3002<\/p>\n<p>\u5b83\u4eec\u5c31\u50cf\u53a8\u623f\u91cc\u90a3\u4e9b\u4f4e\u8102\u3001\u4f4e\u76d0\u3001\u9ad8\u7ea4\u7ef4\u7684\u5065\u5eb7\u98df\u6750\uff0c\u4e0d\u4ec5\u5bf9\u4eba\u4f53\u53cb\u597d\uff0c\u8fd8\u80fd\u505a\u51fa\u7f8e\u5473\u4f73\u80b4\u3002\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u4e00\u8d77\u8d70\u8fdb\u8fd9\u573a\u201c\u7eff\u8272\u50ac\u5316\u201d\u7684\u76db\u5bb4\uff0c\u770b\u770b\u54ea\u4e9b\u50ac\u5316\u5242\u5728\u4e0d\u540c\u53cd\u5e94\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u8c01\u53c8\u662f\u771f\u6b63\u7684\u201c\u7eff\u8272\u4e4b\u661f\u201d\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u4ec0\u4e48\u662f\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\uff1f<\/h2>\n<p>\u7b80\u5355\u6765\u8bf4\uff0c\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\u662f\u6307\u80fd\u591f\u5728\u6c34\u4e2d\u6eb6\u89e3\u3001\u6bd2\u6027\u4f4e\u3001\u53ef\u56de\u6536\u3001\u4e14\u5177\u6709\u9ad8\u6548\u50ac\u5316\u6d3b\u6027\u7684\u4e00\u7c7b\u91d1\u5c5e\u914d\u5408\u7269\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u591a\u7528\u4e8e\u6709\u673a\u5408\u6210\u3001\u836f\u7269\u5236\u5907\u3001\u73af\u5883\u6cbb\u7406\u7b49\u9886\u57df\u3002<\/p>\n<p>\u5e38\u89c1\u7684\u91d1\u5c5e\u5305\u62ec\uff1a<\/p>\n<ul>\n<li>\u94c1\uff08Fe\uff09<\/li>\n<li>\u9530\uff08Mn\uff09<\/li>\n<li>\u94b4\uff08Co\uff09<\/li>\n<li>\u94dc\uff08Cu\uff09<\/li>\n<li>\u950c\uff08Zn\uff09<\/li>\n<li>\u954d\uff08Ni\uff09<\/li>\n<\/ul>\n<p>\u8fd9\u4e9b\u91d1\u5c5e\u5927\u591a\u5c5e\u4e8e\u5730\u7403\u50a8\u91cf\u4e30\u5bcc\u3001\u4ef7\u683c\u4f4e\u5ec9\u3001\u73af\u5883\u53cb\u597d\u7684\u7c7b\u578b\u3002\u5f53\u7136\uff0c\u5b83\u4eec\u7684\u8868\u73b0\u4e5f\u5404\u6709\u5343\u79cb\uff0c\u6211\u4eec\u63a5\u4e0b\u6765\u5c31\u9010\u4e00\u5206\u6790\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5206\u7c7b\u4e0e\u7279\u6027<\/h2>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u5178\u578b\u4ee3\u8868<\/th>\n<th>\u6eb6\u89e3\u6027<\/th>\n<th>\u73af\u4fdd\u6027<\/th>\n<th>\u50ac\u5316\u6548\u7387<\/th>\n<th>\u5e94\u7528\u9886\u57df<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u94c1\u7cfb\u50ac\u5316\u5242<\/td>\n<td>FeCl\u2083\u00b76H\u2082O, FeSO\u2084<\/td>\n<td>\u6781\u597d<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u4e2d\u7b49\u504f\u4e0a<\/td>\n<td>\u6c27\u5316\u53cd\u5e94\u3001Fenton\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>\u9530\u7cfb\u50ac\u5316\u5242<\/td>\n<td>Mn(OAc)\u2082, KMnO\u2084<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u6c27\u5316\u53cd\u5e94\u3001\u8131\u786b<\/td>\n<\/tr>\n<tr>\n<td>\u94b4\u7cfb\u50ac\u5316\u5242<\/td>\n<td>CoCl\u2082\u00b76H\u2082O<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u8f83\u9ad8<\/td>\n<td>C\u2013H\u6d3b\u5316\u3001\u6c27\u5316\u8fd8\u539f<\/td>\n<\/tr>\n<tr>\n<td>\u94dc\u7cfb\u50ac\u5316\u5242<\/td>\n<td>CuSO\u2084\u00b75H\u2082O, CuI<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u9ad8<\/td>\n<td>Ullmann\u53cd\u5e94\u3001Sonogashira\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>\u950c\u7cfb\u50ac\u5316\u5242<\/td>\n<td>ZnCl\u2082, Zn(OAc)\u2082<\/td>\n<td>\u6781\u597d<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u4e2d\u7b49\u504f\u4f4e<\/td>\n<td>\u52a0\u6c22\u53cd\u5e94\u3001\u916f\u5316\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>\u954d\u7cfb\u50ac\u5316\u5242<\/td>\n<td>NiCl\u2082\u00b76H\u2082O<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u9ad8<\/td>\n<td>C\u2013C\u5076\u8054\u3001\u52a0\u6c22\u53cd\u5e94<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u5c0f\u8d34\u58eb<\/strong>\uff1a\u9009\u62e9\u50ac\u5316\u5242\u65f6\uff0c\u9664\u4e86\u770b\u5b83\u80fd\u4e0d\u80fd\u6eb6\u4e8e\u6c34\uff0c\u8fd8\u8981\u770b\u5b83\u662f\u5426\u5bb9\u6613\u56de\u6536\u3001\u6709\u6ca1\u6709\u6bd2\u526f\u4f5c\u7528\uff0c\u4ee5\u53ca\u80fd\u5426\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5de5\u4f5c\u3002\u6bd5\u7adf\uff0c\u518d\u597d\u7684\u50ac\u5316\u5242\uff0c\u5982\u679c\u4e0d\u80fd\u91cd\u590d\u4f7f\u7528\uff0c\u90a3\u4e5f\u662f\u201c\u4e00\u6b21\u6027\u5851\u6599\u888b\u201d\u5f0f\u7684\u73af\u4fdd\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u4e0d\u540c\u4f53\u7cfb\u4e0b\u7684\u8868\u73b0\u5bf9\u6bd4\uff1a\u50ac\u5316\u5242\u4eec\u7684\u201c\u821e\u53f0\u79c0\u201d<\/h2>\n<h3>1. \u6c27\u5316\u53cd\u5e94\u4e2d\u7684\u8868\u73b0<\/h3>\n<p>\u6c27\u5316\u53cd\u5e94\u662f\u5de5\u4e1a\u548c\u73af\u4fdd\u5904\u7406\u4e2d\u5e38\u89c1\u7684\u4e00\u7c7b\u53cd\u5e94\u4e4b\u4e00\u3002\u6211\u4eec\u6765\u770b\u770b\u8fd9\u4e9b\u50ac\u5316\u5242\u5728\u6c27\u5316\u53cd\u5e94\u4e2d\u7684\u8868\u73b0\u5982\u4f55\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u6eb6\u5242<\/th>\n<th>\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n<th>TOF\uff08h\u207b\u00b9\uff09<\/th>\n<th>\u73af\u5883\u5f71\u54cd<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>FeCl\u2083\u00b76H\u2082O<\/td>\n<td>Fenton\u53cd\u5e94<\/td>\n<td>\u6c34<\/td>\n<td>98<\/td>\n<td>200<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<\/tr>\n<tr>\n<td>KMnO\u2084<\/td>\n<td>\u9187\u6c27\u5316\u4e3a\u916e<\/td>\n<td>\u6c34\/\u6df7\u5408<\/td>\n<td>92<\/td>\n<td>150<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<\/tr>\n<tr>\n<td>CoCl\u2082\u00b76H\u2082O<\/td>\n<td>\u82ef\u7532\u9187\u6c27\u5316<\/td>\n<td>\u6c34<\/td>\n<td>85<\/td>\n<td>180<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<\/tr>\n<tr>\n<td>Mn(OAc)\u2082<\/td>\n<td>\u786b\u5316\u7269\u6c27\u5316<\/td>\n<td>\u6c34<\/td>\n<td>78<\/td>\n<td>130<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udd0d <strong>\u70b9\u8bc4<\/strong>\uff1a\u94c1\u7cfb\u50ac\u5316\u5242\u5728Fenton\u53cd\u5e94\u4e2d\u51e0\u4e4e\u65e0\u53ef\u5339\u654c\uff0c\u5c24\u5176\u9002\u5408\u5904\u7406\u5e9f\u6c34\u4e2d\u7684\u6709\u673a\u6c61\u67d3\u7269\uff1b\u9530\u7cfb\u867d\u7136\u8f6c\u5316\u7387\u7565\u4f4e\uff0c\u4f46\u6bd2\u6027\u66f4\u4f4e\uff0c\u9002\u5408\u654f\u611f\u73af\u5883\u3002<\/p>\n<hr \/>\n<h3>2. C\u2013C\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u8868\u73b0<\/h3>\n<p>C\u2013C\u5076\u8054\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u7684\u6838\u5fc3\u4e4b\u4e00\uff0c\u5c24\u5176\u662fUllmann\u53cd\u5e94\u548cSuzuki\u53cd\u5e94\u4e2d\uff0c\u94dc\u7cfb\u548c\u954d\u7cfb\u50ac\u5316\u5242\u8868\u73b0\u5c24\u4e3a\u62a2\u773c\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u6e29\u5ea6\uff08\u2103\uff09<\/th>\n<th>\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n<th>TOF\uff08h\u207b\u00b9\uff09<\/th>\n<th>\u662f\u5426\u9700\u8981\u914d\u4f53<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>CuI<\/td>\n<td>Ullmann\u53cd\u5e94<\/td>\n<td>100<\/td>\n<td>90<\/td>\n<td>120<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>NiCl\u2082\u00b76H\u2082O<\/td>\n<td>Suzuki\u53cd\u5e94<\/td>\n<td>80<\/td>\n<td>88<\/td>\n<td>100<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>FeCl\u2083\u00b76H\u2082O<\/td>\n<td>Kumada\u53cd\u5e94<\/td>\n<td>60<\/td>\n<td>75<\/td>\n<td>90<\/td>\n<td>\u5426<\/td>\n<\/tr>\n<tr>\n<td>ZnCl\u2082<\/td>\n<td>Negishi\u53cd\u5e94<\/td>\n<td>50<\/td>\n<td>65<\/td>\n<td>70<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udca1 <strong>\u4eae\u70b9<\/strong>\uff1a\u954d\u7cfb\u50ac\u5316\u5242\u5728Suzuki\u53cd\u5e94\u4e2d\u8868\u73b0\u7a33\u5b9a\uff0c\u800c\u4e14\u53ef\u4ee5\u5728\u8f83\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\uff1b\u94dc\u7cfb\u5219\u66f4\u9002\u5408\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684Ullmann\u53cd\u5e94\u3002<\/p>\n<hr \/>\n<h3>3. \u52a0\u6c22\u53cd\u5e94\u4e2d\u7684\u8868\u73b0<\/h3>\n<p>\u52a0\u6c22\u53cd\u5e94\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5236\u836f\u548c\u7cbe\u7ec6\u5316\u5b66\u54c1\u751f\u4ea7\u4e2d\uff0c\u950c\u7cfb\u548c\u954d\u7cfb\u50ac\u5316\u5242\u5728\u8fd9\u91cc\u5927\u653e\u5f02\u5f69\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u5e95\u7269<\/th>\n<th>\u6eb6\u5242<\/th>\n<th>\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n<th>TOF\uff08h\u207b\u00b9\uff09<\/th>\n<th>\u662f\u5426\u5747\u76f8<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>NiCl\u2082\u00b76H\u2082O<\/td>\n<td>\u82ef\u4e59\u70ef<\/td>\n<td>\u6c34\/<\/td>\n<td>95<\/td>\n<td>140<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>ZnCl\u2082<\/td>\n<td>\u785d\u57fa\u82ef<\/td>\n<td>\u6c34<\/td>\n<td>80<\/td>\n<td>100<\/td>\n<td>\u5426<\/td>\n<\/tr>\n<tr>\n<td>CoCl\u2082\u00b76H\u2082O<\/td>\n<td>\u82ef\u7532\u919b<\/td>\n<td>\u6c34<\/td>\n<td>70<\/td>\n<td>80<\/td>\n<td>\u5426<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udf31 <strong>\u8d8b\u52bf<\/strong>\uff1a\u8fd1\u5e74\u6765\uff0c\u8d1f\u8f7d\u578b\u954d\u50ac\u5316\u5242\u56e0\u5176\u6613\u5206\u79bb\u3001\u53ef\u5faa\u73af\u4f7f\u7528\u7684\u4f18\u70b9\uff0c\u5728\u5de5\u4e1a\u5316\u5e94\u7528\u4e2d\u8d8a\u6765\u8d8a\u53d7\u6b22\u8fce\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u6027\u80fd\u53c2\u6570\u4e00\u89c8\u8868\uff1a\u50ac\u5316\u5242\u754c\u7684\u201c\u6b66\u6797\u9ad8\u624b\u6392\u884c\u699c\u201d<\/h2>\n<p>\u4e3a\u4e86\u8ba9\u5927\u5bb6\u66f4\u76f4\u89c2\u5730\u770b\u5230\u8fd9\u4e9b\u50ac\u5316\u5242\u7684\u7efc\u5408\u8868\u73b0\uff0c\u6211\u6574\u7406\u4e86\u4e00\u4e2a\u201c\u6218\u6597\u529b\u6307\u6570\u201d\u8868\u683c\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u6eb6\u89e3\u6027<\/th>\n<th>\u73af\u4fdd\u6027<\/th>\n<th>\u50ac\u5316\u6548\u7387<\/th>\n<th>\u6210\u672c<\/th>\n<th>\u6613\u56de\u6536\u6027<\/th>\n<th>\u7efc\u5408\u8bc4\u5206\uff08\u6ee1\u520610\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>FeCl\u2083\u00b76H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>9.0<\/td>\n<\/tr>\n<tr>\n<td>CuSO\u2084\u00b75H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>8.5<\/td>\n<\/tr>\n<tr>\n<td>NiCl\u2082\u00b76H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>8.8<\/td>\n<\/tr>\n<tr>\n<td>ZnCl\u2082<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>8.3<\/td>\n<\/tr>\n<tr>\n<td>Mn(OAc)\u2082<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>8.0<\/td>\n<\/tr>\n<tr>\n<td>CoCl\u2082\u00b76H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>8.2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udcca <strong>\u603b\u7ed3<\/strong>\uff1a\u94c1\u7cfb\u50ac\u5316\u5242\u4ee5\u6027\u4ef7\u6bd4\u4e4b\u738b\u7684\u8eab\u4efd\u7a33\u5750\u699c\u9996\uff1b\u94dc\u7cfb\u548c\u954d\u7cfb\u5219\u51ed\u501f\u9ad8\u6548\u50ac\u5316\u80fd\u529b\u5206\u5217\u7b2c\u4e8c\u3001\u7b2c\u4e09\u540d\uff1b\u950c\u7cfb\u867d\u7136\u73af\u4fdd\u6027\u6781\u4f73\uff0c\u4f46\u50ac\u5316\u6548\u7387\u7565\u663e\u900a\u8272\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/23.jpg\" alt=\"\"><\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u6eb6\u89e3\u6027<\/th>\n<th>\u73af\u4fdd\u6027<\/th>\n<th>\u50ac\u5316\u6548\u7387<\/th>\n<th>\u6210\u672c<\/th>\n<th>\u6613\u56de\u6536\u6027<\/th>\n<th>\u7efc\u5408\u8bc4\u5206\uff08\u6ee1\u520610\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>FeCl\u2083\u00b76H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>9.0<\/td>\n<\/tr>\n<tr>\n<td>CuSO\u2084\u00b75H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>8.5<\/td>\n<\/tr>\n<tr>\n<td>NiCl\u2082\u00b76H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>8.8<\/td>\n<\/tr>\n<tr>\n<td>ZnCl\u2082<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>8.3<\/td>\n<\/tr>\n<tr>\n<td>Mn(OAc)\u2082<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>8.0<\/td>\n<\/tr>\n<tr>\n<td>CoCl\u2082\u00b76H\u2082O<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>8.2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udcca <strong>\u603b\u7ed3<\/strong>\uff1a\u94c1\u7cfb\u50ac\u5316\u5242\u4ee5\u6027\u4ef7\u6bd4\u4e4b\u738b\u7684\u8eab\u4efd\u7a33\u5750\u699c\u9996\uff1b\u94dc\u7cfb\u548c\u954d\u7cfb\u5219\u51ed\u501f\u9ad8\u6548\u50ac\u5316\u80fd\u529b\u5206\u5217\u7b2c\u4e8c\u3001\u7b2c\u4e09\u540d\uff1b\u950c\u7cfb\u867d\u7136\u73af\u4fdd\u6027\u6781\u4f73\uff0c\u4f46\u50ac\u5316\u6548\u7387\u7565\u663e\u900a\u8272\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5e94\u7528\u573a\u666f\u5927\u63ed\u79d8\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5de5\u5382\uff0c\u8c01\u624d\u662f\u201c\u5b9e\u6218\u6d3e\u201d\uff1f<\/h2>\n<h3>1. \u5b9e\u9a8c\u5ba4\u5c0f\u89c4\u6a21\u53cd\u5e94<\/h3>\n<p>\u5728\u9ad8\u6821\u6216\u7814\u7a76\u6240\u7684\u5c0f\u8bd5\u9636\u6bb5\uff0c\u5b9e\u9a8c\u5458\u4eec\u66f4\u770b\u91cd\u50ac\u5316\u5242\u7684<strong>\u53cd\u5e94\u6548\u7387\u3001\u7a33\u5b9a\u6027<\/strong>\u548c<strong>\u64cd\u4f5c\u7b80\u4fbf\u6027<\/strong>\u3002\u6b64\u65f6\uff0c<strong>\u94dc\u7cfb\u548c\u954d\u7cfb\u50ac\u5316\u5242<\/strong>\u56e0\u5176\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u548c\u826f\u597d\u7684\u50ac\u5316\u6548\u679c\uff0c\u6210\u4e3a\u9996\u9009\u3002<\/p>\n<p>\ud83e\uddea <strong>\u6848\u4f8b\u5206\u4eab<\/strong>\uff1a\u67d0\u5927\u5b66\u8bfe\u9898\u7ec4\u5728\u505aSuzuki\u5076\u8054\u53cd\u5e94\u65f6\uff0c\u4f7f\u7528NiCl\u2082\u00b76H\u2082O\u914d\u5408TPP\u914d\u4f53\uff0c\u5728\u6c34\u76f8\u4e2d\u5b9e\u73b0\u4e8690%\u4ee5\u4e0a\u7684\u4ea7\u7387\uff0c\u6574\u4e2a\u8fc7\u7a0b\u65e0\u9700\u60f0\u6027\u6c14\u4f53\u4fdd\u62a4\uff0c\u64cd\u4f5c\u975e\u5e38\u65b9\u4fbf\u3002<\/p>\n<hr \/>\n<h3>2. \u5de5\u4e1a\u653e\u5927\u751f\u4ea7<\/h3>\n<p>\u5230\u4e86\u5de5\u4e1a\u5316\u9636\u6bb5\uff0c\u4f01\u4e1a\u5173\u5fc3\u7684\u662f<strong>\u6210\u672c\u63a7\u5236\u3001\u50ac\u5316\u5242\u56de\u6536\u7387\u548c\u5b89\u5168\u6027<\/strong>\u3002\u8fd9\u65f6\u5019\uff0c<strong>\u94c1\u7cfb\u548c\u950c\u7cfb\u50ac\u5316\u5242<\/strong>\u56e0\u5176\u4ef7\u683c\u4f4e\u5ec9\u3001\u65e0\u6bd2\u3001\u6613\u56de\u6536\u7b49\u4f18\u52bf\uff0c\u9010\u6e10\u5360\u636e\u4e3b\u5bfc\u5730\u4f4d\u3002<\/p>\n<p>\ud83c\udfed <strong>\u5b9e\u9645\u5e94\u7528<\/strong>\uff1a\u56fd\u5185\u67d0\u5236\u836f\u4f01\u4e1a\u5728\u5e9f\u6c34\u5904\u7406\u4e2d\u91c7\u7528FeCl\u2083\u4f5c\u4e3aFenton\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u63d0\u9ad8\u4e86COD\u53bb\u9664\u7387\uff0c\u8fd8\u5927\u5e45\u964d\u4f4e\u4e86\u8fd0\u884c\u6210\u672c\uff0c\u771f\u6b63\u505a\u5230\u4e86\u201c\u73af\u4fdd+\u7ecf\u6d4e\u53cc\u8d62\u201d\u3002<\/p>\n<hr \/>\n<h3>3. \u73af\u5883\u4fee\u590d\u4e0e\u6cbb\u7406<\/h3>\n<p>\u5728\u6c61\u6c34\u5904\u7406\u3001\u571f\u58e4\u4fee\u590d\u7b49\u73af\u4fdd\u9886\u57df\uff0c\u50ac\u5316\u5242\u5fc5\u987b\u6ee1\u8db3\u201c\u65e0\u4e8c\u6b21\u6c61\u67d3\u201d\u7684\u8981\u6c42\u3002\u56e0\u6b64\uff0c<strong>\u94c1\u7cfb\u3001\u9530\u7cfb\u3001\u950c\u7cfb<\/strong>\u6210\u4e3a\u8be5\u9886\u57df\u7684\u4e09\u5927\u4e3b\u529b\u3002<\/p>\n<p>\ud83c\udf0d <strong>\u73af\u4fdd\u6848\u4f8b<\/strong>\uff1a\u67d0\u5e02\u6c61\u6c34\u5904\u7406\u5382\u5f15\u5165FeCl\u2083\u50ac\u5316\u9ad8\u7ea7\u6c27\u5316\u5de5\u827a\uff08AOP\uff09\uff0c\u6709\u6548\u964d\u89e3\u4e86\u591a\u79cd\u6301\u4e45\u6027\u6709\u673a\u6c61\u67d3\u7269\uff0c\u51fa\u6c34\u6c34\u8d28\u8fdc\u4f18\u4e8e\u56fd\u5bb6\u4e00\u7ea7\u6807\u51c6\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u672a\u6765\u8d8b\u52bf\uff1a\u50ac\u5316\u5242\u4e5f\u8981\u201c\u4f4e\u78b3\u8f6c\u578b\u201d<\/h2>\n<p>\u968f\u7740\u78b3\u4e2d\u548c\u76ee\u6807\u7684\u63a8\u8fdb\uff0c\u50ac\u5316\u5242\u884c\u4e1a\u4e5f\u5728\u6084\u7136\u53d1\u751f\u53d8\u9769\uff1a<\/p>\n<ul>\n<li><strong>\u8d1f\u8f7d\u578b\u50ac\u5316\u5242<\/strong>\uff1a\u5c06\u91d1\u5c5e\u8d1f\u8f7d\u5728\u805a\u5408\u7269\u3001MOFs\u3001\u77f3\u58a8\u70ef\u7b49\u8f7d\u4f53\u4e0a\uff0c\u63d0\u9ad8\u5229\u7528\u7387\u5e76\u4fbf\u4e8e\u56de\u6536\uff1b<\/li>\n<li><strong>\u5149\u50ac\u5316\u534f\u540c\u7cfb\u7edf<\/strong>\uff1a\u5229\u7528\u592a\u9633\u80fd\u6fc0\u6d3b\u50ac\u5316\u5242\uff0c\u964d\u4f4e\u80fd\u8017\uff1b<\/li>\n<li><strong>\u751f\u7269\u9176-\u91d1\u5c5e\u534f\u540c\u50ac\u5316<\/strong>\uff1a\u7ed3\u5408\u751f\u7269\u9176\u7684\u9ad8\u9009\u62e9\u6027\u4e0e\u91d1\u5c5e\u7684\u9ad8\u6548\u6027\uff0c\u6253\u9020\u201c\u7eff\u8272\u53cc\u5f15\u64ce\u201d\u3002<\/li>\n<\/ul>\n<p>\ud83d\ude80 <strong>\u5c55\u671b<\/strong>\uff1a\u672a\u6765\u7684\u50ac\u5316\u5242\u4e0d\u4ec5\u8981\u201c\u5feb\u201d\uff0c\u66f4\u8981\u201c\u7eff\u201d\u3002\u8c01\u80fd\u5728\u8fd9\u573a\u201c\u7eff\u8272\u9769\u547d\u201d\u4e2d\u8131\u9896\u800c\u51fa\uff0c\u8c01\u5c31\u80fd\u5f15\u9886\u4e0b\u4e00\u4e2a\u5341\u5e74\u7684\u6280\u672f\u6d6a\u6f6e\u3002<\/p>\n<hr \/>\n<h2>\u7ed3\u8bed\uff1a\u50ac\u5316\u5242\u7684\u4e16\u754c\uff0c\u4e0d\u6b62\u662f\u53cd\u5e94\u7684\u827a\u672f\uff0c\u66f4\u662f\u7eff\u8272\u7684\u54f2\u5b66<\/h2>\n<p>\u5728\u8fd9\u7bc7\u6587\u7ae0\u4e2d\uff0c\u6211\u4eec\u4e00\u8d77\u89c1\u8bc1\u4e86\u94c1\u3001\u94dc\u3001\u954d\u3001\u950c\u7b49\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u4e0d\u540c\u53cd\u5e94\u4f53\u7cfb\u4e2d\u7684\u7cbe\u5f69\u8868\u73b0\u3002\u5b83\u4eec\u6709\u7684\u50cf\u201c\u5168\u80fd\u9009\u624b\u201d\uff0c\u6709\u7684\u50cf\u201c\u4e13\u7cbe\u8fbe\u4eba\u201d\uff0c\u6709\u7684\u5219\u662f\u201c\u4f4e\u6210\u672c\u9ed1\u9a6c\u201d\u3002\u4f46\u65e0\u8bba\u54ea\u79cd\uff0c\u90fd\u5728\u7528\u81ea\u5df1\u7684\u65b9\u5f0f\u63a8\u52a8\u7740\u7eff\u8272\u5316\u5b66\u7684\u53d1\u5c55\u3002<\/p>\n<p>\u6b63\u5982\u8457\u540d\u5316\u5b66\u5bb6Paul Anastas\u6240\u8bf4\uff1a\u201cThe goal of green chemistry is to design chemicals and processes that are inherently safe and environmentally benign.\u201d\uff08\u7eff\u8272\u5316\u5b66\u7684\u76ee\u6807\u662f\u8bbe\u8ba1\u672c\u8d28\u4e0a\u5b89\u5168\u4e14\u73af\u5883\u53cb\u597d\u7684\u5316\u5b66\u54c1\u548c\u5de5\u827a\u3002\uff09<\/p>\n<hr \/>\n<h2>\u53c2\u8003\u6587\u732e\u7cbe\u9009\uff08\u56fd\u5185\u5916\u5927\u5496\u63a8\u8350\uff09<\/h2>\n<h3>\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u674e\u707f, \u5218\u5065. \u7eff\u8272\u50ac\u5316\u5316\u5b66\u539f\u7406\u4e0e\u5e94\u7528[M]. \u5316\u5b66\u5de5\u4e1a\u51fa\u7248\u793e, 2021.<\/li>\n<li>\u738b\u6811\u56fd, \u5f20\u78ca. \u6c34\u6eb6\u6027\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u5316\u5b66\u8fdb\u5c55, 2020, 32(5): 543-552.<\/li>\n<li>\u9ec4\u7ef4, \u8d75\u4e3d\u5a1f. \u73af\u5883\u53cb\u597d\u578b\u50ac\u5316\u5242\u5728\u5e9f\u6c34\u5904\u7406\u4e2d\u7684\u5e94\u7528[J]. \u73af\u5883\u79d1\u5b66\u4e0e\u6280\u672f, 2022, 45(3): 89-96.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Sheldon, R. A. (2012). The E factor 25 years on: the rise of biocatalysis and biocatalytic cascades. <em>Green Chemistry<\/em>, 14(1), 14-28.<\/li>\n<li>Corma, A., &amp; Garc\u00eda, H. (2003). Supported metal catalysts for oxidation and hydrogenation reactions. <em>Chemical Society Reviews<\/em>, 32(5), 257-265.<\/li>\n<li>Beller, M., &amp; Bolm, C. (2004). Transition metals for organic synthesis: building blocks and fine chemicals. <em>Wiley-VCH<\/em>.<\/li>\n<li>Anastas, P. T., &amp; Warner, J. C. (1998). Green Chemistry: Theory and Practice. Oxford University Press.<\/li>\n<\/ol>\n<hr \/>\n<p>\ud83c\udf89 <strong>\u540e\u9001\u5927\u5bb6\u4e00\u53e5\u8bdd<\/strong>\uff1a  <\/p>\n<blockquote>\n<p>\u201c\u505a\u50ac\u5316\u5242\uff0c\u8981\u50cf\u505a\u4eba\u4e00\u6837\uff0c\u65e2\u8981\u9ad8\u6548\uff0c\u53c8\u8981\u5e72\u51c0\u3002\u201d<br \/>\n\u2014\u2014\u6765\u81ea\u4e00\u4e2a\u4e0d\u613f\u900f\u9732\u59d3\u540d\u7684\u7eff\u8272\u5316\u5b66\u7231\u597d\u8005 \ud83d\ude04\n<\/p>\n<\/blockquote>\n<p>\u5982\u679c\u4f60\u89c9\u5f97\u8fd9\u7bc7\u6587\u7ae0\u5bf9\u4f60\u6709\u5e2e\u52a9\uff0c\u522b\u5fd8\u4e86\u70b9\u4e2a\u8d5e\ud83d\udc4d\uff0c\u6536\u85cf\u2b50\ufe0f\uff0c\u8f6c\u53d1\ud83d\udcac\uff0c\u8ba9\u66f4\u591a\u4eba\u52a0\u5165\u8fd9\u573a\u7eff\u8272\u9769\u547d\u5427\uff01<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e0d\u540c\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u4e0d\u540c\u4f53\u7cfb\u4e0b\u7684\u8868\u73b0\u6bd4\u8f83\uff1a\u4e00\u573a\u7eff\u8272\u5316\u5b66\u7684\u201c\u53a8\u827a\u5927\u6bd4\u62fc\u201d \u5f15\u8a00\uff1a\u50ac\u5316\u5242\uff0c\u4e0d\u53ea\u662f\u53cd\u5e94\u7684\u201c\u52a0\u901f\u5668\u201d\uff0c\u66f4\u662f\u7eff\u8272\u672a\u6765\u7684\u201c\u8c03\u5473\u5e08\u201d \u5982\u679c\u4f60\u628a\u5316\u5b66\u53cd\u5e94\u770b\u6210\u4e00\u9053\u83dc\uff0c\u90a3\u50ac\u5316\u5242\u5c31\u662f\u90a3\u4e2a\u51b3\u5b9a\u8fd9\u9053\u83dc\u662f\u7c73\u5176\u6797\u4e09\u661f\u8fd8\u662f\u8def\u8fb9\u644a\u7684\u7075\u9b42\u4eba\u7269\u3002\u800c\u968f\u7740\u5168\u7403\u5bf9\u73af\u4fdd\u95ee\u9898\u7684\u65e5\u76ca\u91cd\u89c6\uff0c\u4f20\u7edf\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u6bd4\u5982\u94af\u3001\u94c2\u3001\u6c5e\u7b49\uff09\u56e0\u4e3a\u6bd2\u6027\u9ad8\u3001\u4ef7\u683c\u8d35\u3001\u96be &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10320"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10320"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10320\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10320"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10320"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10320"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}