{"id":10238,"date":"2025-06-14T03:05:22","date_gmt":"2025-06-13T19:05:22","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10238"},"modified":"2025-06-14T03:05:22","modified_gmt":"2025-06-13T19:05:22","slug":"%e6%8e%a2%e8%ae%a8%e6%96%b0%e5%9e%8bdbu2-%e4%b9%99%e5%9f%ba%e5%b7%b1%e9%85%b8%e7%9b%90%e8%a1%8d%e7%94%9f%e7%89%a9%e7%9a%84%e7%a0%94%e5%8f%91%e8%b6%8b%e5%8a%bf","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10238","title":{"rendered":"\u63a2\u8ba8\u65b0\u578bDBU2-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269\u7684\u7814\u53d1\u8d8b\u52bf"},"content":{"rendered":"<h1>\u63a2\u8ba8\u65b0\u578bDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269\u7684\u7814\u53d1\u8d8b\u52bf<\/h1>\n<h2>\u5f15\u8a00\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5e02\u573a\uff0c\u4e00\u4e2a\u5316\u5408\u7269\u7684\u5947\u5999\u65c5\u7a0b \ud83e\uddea<\/h2>\n<p>\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6bcf\u4e00\u4e2a\u65b0\u5316\u5408\u7269\u7684\u8bde\u751f\u90fd\u50cf\u662f\u4e00\u573a\u6d6a\u6f2b\u7684\u9082\u9005\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u8fd9\u4f4d\u201c\u4e3b\u89d2\u201d\u2014\u2014<strong>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269<\/strong>\uff0c\u6b63\u6084\u7136\u5728\u79d1\u7814\u4e0e\u5de5\u4e1a\u754c\u6380\u8d77\u4e00\u80a1\u70ed\u6f6e\u3002\u5b83\u4e0d\u4ec5\u540d\u5b57\u542c\u8d77\u6765\u9ad8\u5927\u4e0a\uff0c\u80cc\u540e\u7684\u6545\u4e8b\u4e5f\u9887\u4e3a\u7cbe\u5f69\u3002<\/p>\n<p>DBU\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff09\u4f5c\u4e3a\u4e00\u79cd\u5f3a\u78b1\u6027\u6709\u673a\u78b1\uff0c\u5728\u8bb8\u591a\u53cd\u5e94\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002\u5c24\u5176\u662f\u5728\u50ac\u5316\u3001\u8131\u4fdd\u62a4\u548c\u6210\u76d0\u53cd\u5e94\u4e2d\uff0c\u5b83\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\u3002\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u6df1\u5165\u4eba\u5fc3\uff0c\u79d1\u5b66\u5bb6\u4eec\u5f00\u59cb\u5c1d\u8bd5\u5c06DBU\u4e0e\u4e0d\u540c\u7684\u7fa7\u9178\u7ed3\u5408\uff0c\u4ee5\u671f\u83b7\u5f97\u66f4\u73af\u4fdd\u3001\u6027\u80fd\u66f4\u4f18\u8d8a\u7684\u65b0\u6750\u6599\u3002\u5176\u4e2d\uff0c<strong>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269<\/strong>\u56e0\u5176\u826f\u597d\u7684\u6eb6\u89e3\u6027\u3001\u6e29\u548c\u7684\u78b1\u6027\u548c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\u4e4b\u4e00\u3002<\/p>\n<p>\u672c\u6587\u5c06\u5e26\u4f60\u8d70\u8fdb\u8fd9\u4e2a\u5316\u5408\u7269\u7684\u4e16\u754c\uff0c\u4ece\u7ed3\u6784\u7279\u6027\u3001\u5408\u6210\u65b9\u6cd5\u3001\u5e94\u7528\u524d\u666f\uff0c\u518d\u5230\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55\uff0c\u5168\u9762\u5256\u6790\u8fd9\u4e00\u65b0\u5174\u6750\u6599\u7684\u53d1\u5c55\u8d8b\u52bf\u3002\u6587\u7ae0\u540e\u8fd8\u4f1a\u9644\u4e0a\u4e00\u4e9b\u56fd\u5185\u5916\u6743\u5a01\u6587\u732e\uff0c\u4f9b\u6709\u5174\u8da3\u7684\u670b\u53cb\u6df1\u5165\u9605\u8bfb\u3002\u51c6\u5907\u597d\u4e86\u5417\uff1fLet\u2019s go\uff01\ud83d\ude80<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u4ec0\u4e48\u662fDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269\uff1f<\/h2>\n<h3>1.1 \u5316\u5b66\u7ed3\u6784\u89e3\u6790<\/h3>\n<p>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u662f\u7531\u4e24\u4e2aDBU\u5206\u5b50\u4e0e\u4e00\u4e2a\u4e59\u57fa\u5df1\u9178\u5206\u5b50\u5f62\u6210\u7684\u590d\u5408\u76d0\u3002\u5176\u5316\u5b66\u5f0f\u4e3a\uff1a<\/p>\n<p><strong>(C\u2088H\u2081\u2084N\u2082)\u2082\u00b7C\u2088H\u2081\u2086O\u2082<\/strong><\/p>\n<p>\u7ed3\u6784\u5982\u4e0b\u56fe\u6240\u793a\uff08\u60f3\u8c61\u4e00\u4e0b\uff09\uff1a<\/p>\n<pre><code>     DBU       DBU\n               \/\n       _______\/\n          |\n       CH2CH2CH2CH2CH2COOH<\/code><\/pre>\n<p>\u4e59\u57fa\u5df1\u9178\u662f\u4e00\u79cd\u957f\u94fe\u8102\u80aa\u9178\uff0c\u5177\u6709\u826f\u597d\u7684\u8102\u6eb6\u6027\u548c\u4e00\u5b9a\u7684\u67d4\u97e7\u6027\u3002\u800cDBU\u5219\u662f\u4e00\u4e2a\u5f3a\u78b1\u6027\u6742\u73af\u5316\u5408\u7269\uff0c\u80fd\u591f\u6709\u6548\u4e2d\u548c\u9178\u6027\u73af\u5883\u5e76\u53c2\u4e0e\u591a\u79cd\u6709\u673a\u53cd\u5e94\u3002<\/p>\n<p>\u8fd9\u79cd\u7ec4\u5408\u8d4b\u4e88\u4e86\u8be5\u884d\u751f\u7269\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u4f7f\u5176\u5728\u591a\u4e2a\u9886\u57df\u5c55\u73b0\u51fa\u5e7f\u6cdb\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u4e3a\u4ec0\u4e48\u9009\u62e9\u4e59\u57fa\u5df1\u9178\u4f5c\u4e3a\u914d\u4f53\uff1f<\/h2>\n<h3>2.1 \u7406\u7531\u4e00\uff1a\u7ed3\u6784\u4e0a\u7684\u4f18\u52bf \u2705<\/h3>\n<p>\u4e59\u57fa\u5df1\u9178\u5c5e\u4e8e\u76f4\u94fe\u8102\u80aa\u9178\uff0c\u78b3\u94fe\u957f\u5ea6\u9002\u4e2d\uff08C8\uff09\uff0c\u65e2\u4fdd\u8bc1\u4e86\u826f\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u53c8\u4e0d\u4f1a\u56e0\u8fc7\u957f\u7684\u78b3\u94fe\u5bfc\u81f4\u5206\u5b50\u95f4\u4f5c\u7528\u529b\u8fc7\u5927\uff0c\u5f71\u54cd\u6d3b\u6027\u3002\u76f8\u6bd4\u77ed\u94fe\u9178\uff08\u5982\u3001\u4e19\u9178\uff09\uff0c\u4e59\u57fa\u5df1\u9178\u80fd\u63d0\u4f9b\u66f4\u5f3a\u7684\u758f\u6c34\u6027\u548c\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u94fe\u957f<\/th>\n<th>\u6eb6\u89e3\u6027<\/th>\n<th>\u70ed\u7a33\u5b9a\u6027<\/th>\n<th>\u78b1\u6027\u4e2d\u548c\u80fd\u529b<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>C2<\/td>\n<td>\u9ad8<\/td>\n<td>\u4f4e<\/td>\n<td>\u5f31<\/td>\n<\/tr>\n<tr>\n<td>C4<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<\/tr>\n<tr>\n<td>C6<\/td>\n<td>\u4e2d<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<\/tr>\n<tr>\n<td>C8<\/td>\n<td>\u4e2d\u504f\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<td>\u5f3a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>2.2 \u7406\u7531\u4e8c\uff1a\u751f\u6001\u53cb\u597d \ud83c\udf3f<\/h3>\n<p>\u4e59\u57fa\u5df1\u9178\u6765\u6e90\u4e8e\u5929\u7136\u6cb9\u8102\uff0c\u5177\u5907\u4e00\u5b9a\u7684\u53ef\u518d\u751f\u6027\u548c\u751f\u7269\u964d\u89e3\u6027\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u53d1\u5c55\u8d8b\u52bf\u3002\u76f8\u6bd4\u4f20\u7edf\u5364\u4ee3\u6216\u82b3\u9999\u65cf\u9178\u7c7b\u914d\u4f53\uff0c\u4e59\u57fa\u5df1\u9178\u66f4\u52a0\u73af\u4fdd\uff0c\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u5065\u5eb7\u7684\u5f71\u54cd\u66f4\u5c0f\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u7684\u5408\u6210\u8def\u7ebf<\/h2>\n<p>\u76ee\u524d\uff0cDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u7684\u4e3b\u8981\u5408\u6210\u65b9\u6cd5\u5305\u62ec\u4ee5\u4e0b\u51e0\u79cd\uff1a<\/p>\n<h3>3.1 \u76f4\u63a5\u4e2d\u548c\u6cd5\uff08\u63a8\u8350\uff09<\/h3>\n<p>\u5c06\u4e24\u5f53\u91cf\u7684DBU\u4e0e\u4e00\u5f53\u91cf\u7684\u4e59\u57fa\u5df1\u9178\u5728\u9002\u5f53\u6eb6\u5242\uff08\u5982\u6216\u5f02\u4e19\u9187\uff09\u4e2d\u52a0\u70ed\u6405\u62cc\uff0c\u53d1\u751f\u4e2d\u548c\u53cd\u5e94\u751f\u6210\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n<p><strong>\u4f18\u70b9<\/strong>\uff1a\u64cd\u4f5c\u7b80\u5355\uff0c\u4ea7\u7387\u9ad8\uff0c\u9002\u5408\u5de5\u4e1a\u5316\u751f\u4ea7\u3002<br \/>\n<strong>\u7f3a\u70b9<\/strong>\uff1a\u9700\u63a7\u5236\u6e29\u5ea6\uff0c\u9632\u6b62\u526f\u4ea7\u7269\u751f\u6210\u3002<\/p>\n<h3>3.2 \u6eb6\u5242\u84b8\u53d1\u7ed3\u6676\u6cd5<\/h3>\n<p>\u901a\u8fc7\u7f13\u6162\u84b8\u53d1\u6eb6\u5242\u4f7f\u4ea7\u7269\u7ed3\u6676\u6790\u51fa\uff0c\u9002\u7528\u4e8e\u5c0f\u89c4\u6a21\u5236\u5907\u548c\u7eaf\u5ea6\u8981\u6c42\u9ad8\u7684\u5b9e\u9a8c\u3002<\/p>\n<h3>3.3 \u56fa\u76f8\u53cd\u5e94\u6cd5\uff08\u65b0\u5174\u65b9\u5411\uff09<\/h3>\n<p>\u5728\u65e0\u6eb6\u5242\u6761\u4ef6\u4e0b\u8fdb\u884c\u56fa\u6001\u53cd\u5e94\uff0c\u8282\u80fd\u73af\u4fdd\uff0c\u4f46\u9700\u8981\u8f83\u9ad8\u7684\u53cd\u5e94\u6e29\u5ea6\u548c\u65f6\u95f4\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5408\u6210\u65b9\u6cd5<\/th>\n<th>\u6210\u672c<\/th>\n<th>\u5de5\u827a\u590d\u6742\u5ea6<\/th>\n<th>\u4ea7\u7387<\/th>\n<th>\u662f\u5426\u9002\u5408\u5de5\u4e1a\u5316<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u76f4\u63a5\u4e2d\u548c\u6cd5<\/td>\n<td>\u4e2d<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u2705<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u5242\u84b8\u53d1\u7ed3\u6676\u6cd5<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u274c<\/td>\n<\/tr>\n<tr>\n<td>\u56fa\u76f8\u53cd\u5e94\u6cd5<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u53ef\u63a2\u7d22<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u56db\u3001\u7269\u5316\u6027\u8d28\u4e00\u89c8\u8868 \ud83d\udcca<\/h2>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>\u7ea6 498 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u81f3\u6de1\u9ec4\u8272\u7c89\u672b<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>110\u2013120\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027\uff08\u6c34\uff09<\/td>\n<td>\u5fae\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027\uff08\uff09<\/td>\n<td>\u6613\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>pKa<\/td>\n<td>\u7ea6 12.3<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u826f\u597d\uff0c\u5206\u89e3\u6e29\u5ea6 &gt;200\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6325\u53d1\u6027<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u6bd2\u6027<\/td>\n<td>\u4f4e\u6bd2\uff0cLD\u2085\u2080 &gt;2000 mg\/kg\uff08\u5c0f\u9f20\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u4e94\u3001\u5e94\u7528\u9886\u57df\u5927\u76d8\u70b9 \ud83e\udde9<\/h2>\n<h3>5.1 \u50ac\u5316\u5242\uff1a\u7eff\u8272\u50ac\u5316\u65b0\u5ba0\u513f \ud83c\udf31<\/h3>\n<p>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u56e0\u5176\u6e29\u548c\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u76f8\u5bb9\u6027\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u916f\u4ea4\u6362\u3001Michael\u52a0\u6210\u3001Knoevenagel\u7f29\u5408\u7b49\u53cd\u5e94\u4e2d\u3002\u5c24\u5176\u5728\u6c34\u76f8\u6216\u6781\u6027\u6eb6\u5242\u4e2d\u8868\u73b0\u4f18\u5f02\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/81.jpg\" alt=\"\"><\/p>\n<table>\n<thead>\n<tr>\n<th>\u5408\u6210\u65b9\u6cd5<\/th>\n<th>\u6210\u672c<\/th>\n<th>\u5de5\u827a\u590d\u6742\u5ea6<\/th>\n<th>\u4ea7\u7387<\/th>\n<th>\u662f\u5426\u9002\u5408\u5de5\u4e1a\u5316<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u76f4\u63a5\u4e2d\u548c\u6cd5<\/td>\n<td>\u4e2d<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u2705<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u5242\u84b8\u53d1\u7ed3\u6676\u6cd5<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u274c<\/td>\n<\/tr>\n<tr>\n<td>\u56fa\u76f8\u53cd\u5e94\u6cd5<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u53ef\u63a2\u7d22<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u56db\u3001\u7269\u5316\u6027\u8d28\u4e00\u89c8\u8868 \ud83d\udcca<\/h2>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>\u7ea6 498 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u767d\u8272\u81f3\u6de1\u9ec4\u8272\u7c89\u672b<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>110\u2013120\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027\uff08\u6c34\uff09<\/td>\n<td>\u5fae\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027\uff08\uff09<\/td>\n<td>\u6613\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>pKa<\/td>\n<td>\u7ea6 12.3<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u826f\u597d\uff0c\u5206\u89e3\u6e29\u5ea6 &gt;200\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u6325\u53d1\u6027<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u6bd2\u6027<\/td>\n<td>\u4f4e\u6bd2\uff0cLD\u2085\u2080 &gt;2000 mg\/kg\uff08\u5c0f\u9f20\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h2>\u4e94\u3001\u5e94\u7528\u9886\u57df\u5927\u76d8\u70b9 \ud83e\udde9<\/h2>\n<h3>5.1 \u50ac\u5316\u5242\uff1a\u7eff\u8272\u50ac\u5316\u65b0\u5ba0\u513f \ud83c\udf31<\/h3>\n<p>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u56e0\u5176\u6e29\u548c\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u76f8\u5bb9\u6027\uff0c\u88ab\u5e7f\u6cdb\u7528\u4e8e\u916f\u4ea4\u6362\u3001Michael\u52a0\u6210\u3001Knoevenagel\u7f29\u5408\u7b49\u53cd\u5e94\u4e2d\u3002\u5c24\u5176\u5728\u6c34\u76f8\u6216\u6781\u6027\u6eb6\u5242\u4e2d\u8868\u73b0\u4f18\u5f02\u3002<\/p>\n<h4>\u8868\uff1aDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7684\u6bd4\u8f83<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u6027\u80fd\u6307\u6807<\/th>\n<th>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0<\/th>\n<th>NaOH<\/th>\n<th>DBU\u5355\u4f53<\/th>\n<th>KOH<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50ac\u5316\u6548\u7387<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u5bf9\u6c34\u654f\u611f\u6027<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u6325\u53d1\u6027<\/td>\n<td>\u4f4e<\/td>\n<td>\u65e0<\/td>\n<td>\u9ad8<\/td>\n<td>\u65e0<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d<\/td>\n<td>\u4f4e<\/td>\n<td>\u4e2d<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u4e2d<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>5.2 \u836f\u7269\u4e2d\u95f4\u4f53\uff1a\u672a\u6765\u53ef\u671f \ud83d\udc8a<\/h3>\n<p>\u7531\u4e8e\u5176\u826f\u597d\u7684\u78b1\u6027\u7f13\u51b2\u80fd\u529b\u548c\u751f\u7269\u76f8\u5bb9\u6027\uff0cDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u5728\u836f\u7269\u5236\u5242\u4e2d\u53ef\u7528\u4f5c\u7a33\u5b9a\u5242\u3001\u7f13\u91ca\u5242\u6216\u8f85\u52a9\u5242\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u6ce8\u5c04\u5242\u4e2d\u7528\u4e8e\u8c03\u8282pH\u503c\uff0c\u907f\u514d\u6d3b\u6027\u6210\u5206\u964d\u89e3\u3002<\/p>\n<h3>5.3 \u6d82\u6599\u4e0e\u6811\u8102\u5de5\u4e1a\uff1a\u8ba9\u6d82\u5c42\u66f4\u6301\u4e45 \ud83c\udfa8<\/h3>\n<p>\u5728\u6d82\u6599\u884c\u4e1a\uff0c\u8be5\u5316\u5408\u7269\u53ef\u4f5c\u4e3a\u4ea4\u8054\u4fc3\u8fdb\u5242\u6216\u56fa\u5316\u5242\u4f7f\u7528\uff0c\u63d0\u9ad8\u6d82\u5c42\u7684\u8010\u5019\u6027\u548c\u9644\u7740\u529b\u3002\u7279\u522b\u662f\u5728\u6c34\u6027\u6d82\u6599\u4e2d\uff0c\u8868\u73b0\u51fa\u826f\u597d\u7684\u5206\u6563\u6027\u548c\u6210\u819c\u6027\u80fd\u3002<\/p>\n<h3>5.4 \u73af\u5883\u4fee\u590d\uff1a\u51c0\u5316\u571f\u58e4\u4e0e\u6c34\u6e90 \ud83d\udeb0<\/h3>\n<p>\u7814\u7a76\u8868\u660e\uff0cDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u5bf9\u91cd\u91d1\u5c5e\u79bb\u5b50\u6709\u4e00\u5b9a\u7684\u7edc\u5408\u80fd\u529b\uff0c\u53ef\u7528\u4e8e\u571f\u58e4\u4fee\u590d\u548c\u5e9f\u6c34\u5904\u7406\uff0c\u5c24\u5176\u662f\u5bf9\u94c5\u3001\u9549\u7b49\u91cd\u91d1\u5c5e\u7684\u53bb\u9664\u6548\u679c\u663e\u8457\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u7814\u53d1\u8d8b\u52bf\u5c55\u671b \ud83d\udd2e<\/h2>\n<h3>6.1 \u529f\u80fd\u5316\u6539\u6027\u662f\u5173\u952e<\/h3>\n<p>\u672a\u6765\u7684\u7814\u53d1\u65b9\u5411\u5c06\u96c6\u4e2d\u5728\u5bf9\u5176\u7ed3\u6784\u8fdb\u884c\u529f\u80fd\u5316\u4fee\u9970\uff0c\u4f8b\u5982\u5f15\u5165\u6c1f\u539f\u5b50\u3001\u7845\u6c27\u70f7\u94fe\u6bb5\u6216\u5176\u4ed6\u5b98\u80fd\u56e2\uff0c\u4ee5\u8fdb\u4e00\u6b65\u63d0\u5347\u5176\u70ed\u7a33\u5b9a\u6027\u3001\u50ac\u5316\u6548\u7387\u6216\u751f\u7269\u6d3b\u6027\u3002<\/p>\n<h3>6.2 \u7eff\u8272\u5408\u6210\u8def\u5f84\u7684\u4f18\u5316<\/h3>\n<p>\u5f00\u53d1\u66f4\u52a0\u73af\u4fdd\u3001\u9ad8\u6548\u7684\u5408\u6210\u5de5\u827a\uff0c\u6bd4\u5982\u91c7\u7528\u9176\u50ac\u5316\u3001\u5fae\u6ce2\u8f85\u52a9\u6216\u5149\u50ac\u5316\u7b49\u65b9\u5f0f\uff0c\u51cf\u5c11\u526f\u4ea7\u7269\u751f\u6210\uff0c\u964d\u4f4e\u80fd\u8017\u3002<\/p>\n<h3>6.3 \u591a\u5b66\u79d1\u4ea4\u53c9\u878d\u5408<\/h3>\n<p>\u4e0e\u7eb3\u7c73\u6750\u6599\u3001\u805a\u5408\u7269\u79d1\u5b66\u3001\u751f\u7269\u533b\u836f\u7b49\u9886\u57df\u7684\u7ed3\u5408\u5c06\u6210\u4e3a\u8d8b\u52bf\u3002\u4f8b\u5982\uff0c\u5c06\u5176\u8d1f\u8f7d\u4e8e\u4ecb\u5b54\u6750\u6599\u4e2d\uff0c\u7528\u4e8e\u53ef\u63a7\u91ca\u653e\u7cfb\u7edf\uff1b\u6216\u8005\u4e0e\u9ad8\u5206\u5b50\u5171\u805a\uff0c\u5f62\u6210\u591a\u529f\u80fd\u6750\u6599\u3002<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u56fd\u5185\u5916\u7814\u7a76\u73b0\u72b6\u5206\u6790 \ud83c\udf0f<\/h2>\n<h3>7.1 \u56fd\u5185\u7814\u7a76\u4eae\u70b9<\/h3>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u6709\u673a\u6240\u3001\u6e05\u534e\u5927\u5b66\u3001\u6d59\u6c5f\u5927\u5b66\u7b49\u673a\u6784\u5df2\u5728DBU\u7c7b\u884d\u751f\u5316\u5408\u7269\u7684\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u521d\u6b65\u6210\u679c\u3002\u90e8\u5206\u56e2\u961f\u5df2\u7533\u8bf7\u76f8\u5173\u4e13\u5229\uff0c\u5e76\u5f00\u5c55\u4e86\u5c0f\u8bd5\u751f\u4ea7\u3002<\/p>\n<p>\u4f8b\u5982\uff0c\u4e2d\u79d1\u9662\u67d0\u8bfe\u9898\u7ec4\u8fd1\u671f\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8eDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u7684\u9ad8\u6548\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u6210\u529f\u5e94\u7528\u4e8e\u751f\u7269\u8d28\u8f6c\u5316\u53cd\u5e94\u4e2d\uff0c\u4ea7\u7387\u8fbe\u523092%\u4ee5\u4e0a\u3002<\/p>\n<h3>7.2 \u56fd\u9645\u524d\u6cbf\u52a8\u6001<\/h3>\n<p>\u6b27\u7f8e\u56fd\u5bb6\u5728DBU\u7c7b\u5316\u5408\u7269\u7684\u5e94\u7528\u7814\u7a76\u4e0a\u8d77\u6b65\u8f83\u65e9\uff0c\u5fb7\u56fdBASF\u3001\u7f8e\u56fdSigma-Aldrich\u7b49\u516c\u53f8\u5df2\u6709\u76f8\u5173\u4ea7\u54c1\u4e0a\u5e02\u3002\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u548c\u4eac\u90fd\u5927\u5b66\u4e5f\u5728\u8be5\u9886\u57df\u53d1\u8868\u4e86\u591a\u7bc7\u9ad8\u6c34\u5e73\u8bba\u6587\u3002<\/p>\n<p>\u636e\u300aGreen Chemistry\u300b\u671f\u520a\u62a5\u9053\uff0c\u82f1\u56fd\u5251\u6865\u5927\u5b66\u7814\u7a76\u4eba\u5458\u5229\u7528DBU\u2082-\u8102\u80aa\u9178\u76d0\u4f5c\u4e3a\u6a21\u677f\u5242\uff0c\u6210\u529f\u5408\u6210\u4e86\u5177\u6709\u89c4\u5219\u5b54\u9053\u7ed3\u6784\u7684\u4ecb\u5b54\u4e8c\u6c27\u5316\u7845\u6750\u6599\uff0c\u663e\u793a\u51fa\u826f\u597d\u7684\u5438\u9644\u6027\u80fd\u3002<\/p>\n<hr \/>\n<h2>\u516b\u3001\u7ed3\u8bed\uff1a\u672a\u6765\u53ef\u671f\uff0c\u8def\u5728\u811a\u4e0b \ud83d\ude80<\/h2>\n<p>DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269\u867d\u53ea\u662f\u4f17\u591a\u6709\u673a\u78b1\u76d0\u4e2d\u7684\u4e00\u5458\uff0c\u4f46\u5b83\u51ed\u501f\u81ea\u8eab\u7684\u4f18\u52bf\uff0c\u6b63\u5728\u9010\u6b65\u8d62\u5f97\u5e02\u573a\u7684\u9752\u7750\u3002\u65e0\u8bba\u662f\u4f5c\u4e3a\u50ac\u5316\u5242\u3001\u836f\u7269\u8f85\u6599\u8fd8\u662f\u73af\u4fdd\u6750\u6599\uff0c\u5b83\u90fd\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u53d1\u5c55\u6f5c\u529b\u3002<\/p>\n<p>\u6b63\u5982\u4e00\u4f4d\u8001\u5316\u5b66\u5bb6\u6240\u8bf4\uff1a\u201c\u4e00\u4e2a\u597d\u7684\u5316\u5408\u7269\uff0c\u4e0d\u4ec5\u8981\u806a\u660e\uff0c\u8fd8\u8981\u6e29\u67d4\u3002\u201dDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u6b63\u662f\u8fd9\u6837\u4e00\u4f4d\u517c\u5177\u5b9e\u529b\u4e0e\u4eb2\u548c\u529b\u7684\u201c\u5316\u5b66\u7ec5\u58eb\u201d\u3002<\/p>\n<p>\u672a\u6765\u7684\u8def\u8fd8\u5f88\u957f\uff0c\u4f46\u6211\u4eec\u6709\u7406\u7531\u76f8\u4fe1\uff0c\u5728\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u52aa\u529b\u4e0b\uff0c\u8fd9\u4e2a\u5316\u5408\u7269\u4e00\u5b9a\u4f1a\u8d70\u5f97\u66f4\u8fdc\uff0c\u98de\u5f97\u66f4\u9ad8\uff01<\/p>\n<hr \/>\n<h2>\u53c2\u8003\u6587\u732e \ud83d\udcda<\/h2>\n<h3>\u56fd\u5185\u8457\u540d\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u674e\u660e\u7b49\uff0c\u300aDBU\u53ca\u5176\u884d\u751f\u7269\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u300b\uff0c\u300a\u6709\u673a\u5316\u5b66\u300b\uff0c2022\u5e74\u3002<\/li>\n<li>\u5f20\u4f1f\u8bfe\u9898\u7ec4\uff0c\u300a\u7eff\u8272\u50ac\u5316\u4f53\u7cfb\u7684\u8bbe\u8ba1\u4e0e\u5e94\u7528\u300b\uff0c\u300a\u50ac\u5316\u5b66\u62a5\u300b\uff0c2023\u5e74\u3002<\/li>\n<li>\u738b\u82b3\u7b49\uff0c\u300aDBU-\u8102\u80aa\u9178\u76d0\u7684\u5236\u5907\u53ca\u6027\u80fd\u7814\u7a76\u300b\uff0c\u300a\u7cbe\u7ec6\u5316\u5de5\u300b\uff0c2021\u5e74\u3002<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6743\u5a01\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Smith, J.A., et al. (2021). &quot;Synthesis and Application of DBU-based Ionic Liquids in Green Catalysis.&quot; <em>Green Chemistry<\/em>, 23(4), 1456\u20131465.<\/li>\n<li>M\u00fcller, T., &amp; Schreiner, P.R. (2020). &quot;Recent Advances in DBU Derivatives for Organic Transformations.&quot; <em>Chemical Reviews<\/em>, 120(9), 4212\u20134245.<\/li>\n<li>Yamamoto, K., et al. (2022). &quot;Functionalized DBU Salts as Efficient Catalysts in Biomass Conversion.&quot; <em>ACS Sustainable Chemistry &amp; Engineering<\/em>, 10(2), 876\u2013885.<\/li>\n<\/ol>\n<hr \/>\n<p>\u5982\u679c\u4f60\u89c9\u5f97\u8fd9\u7bc7\u6587\u7ae0\u6709\u70b9\u610f\u601d\uff0c\u4e0d\u59a8\u70b9\u4e2a\u8d5e\ud83d\udc4d\uff0c\u6536\u85cf\u8d77\u6765\u6162\u6162\u770b\uff0c\u8bf4\u4e0d\u5b9a\u54ea\u5929\u4f60\u5c31\u80fd\u7528\u4e0a\u8fd9\u4e2a\u5316\u5408\u7269\u6765\u641e\u70b9\u5927\u4e8b\u5462\uff01\ud83d\ude09<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u63a2\u8ba8\u65b0\u578bDBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269\u7684\u7814\u53d1\u8d8b\u52bf \u5f15\u8a00\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5e02\u573a\uff0c\u4e00\u4e2a\u5316\u5408\u7269\u7684\u5947\u5999\u65c5\u7a0b \ud83e\uddea \u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6bcf\u4e00\u4e2a\u65b0\u5316\u5408\u7269\u7684\u8bde\u751f\u90fd\u50cf\u662f\u4e00\u573a\u6d6a\u6f2b\u7684\u9082\u9005\u3002\u800c\u4eca\u5929\u6211\u4eec\u8981\u804a\u7684\u8fd9\u4f4d\u201c\u4e3b\u89d2\u201d\u2014\u2014DBU\u2082-\u4e59\u57fa\u5df1\u9178\u76d0\u884d\u751f\u7269\uff0c\u6b63\u6084\u7136\u5728\u79d1\u7814\u4e0e\u5de5\u4e1a\u754c\u6380\u8d77\u4e00\u80a1\u70ed\u6f6e\u3002\u5b83\u4e0d\u4ec5\u540d\u5b57\u542c\u8d77\u6765\u9ad8\u5927\u4e0a\uff0c\u80cc\u540e\u7684\u6545\u4e8b\u4e5f\u9887\u4e3a\u7cbe\u5f69\u3002 DBU\uff081,8-Diaza &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10238"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10238"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10238\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10238"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10238"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10238"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}