{"id":10139,"date":"2025-06-12T02:55:10","date_gmt":"2025-06-11T18:55:10","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10139"},"modified":"2025-06-12T02:55:10","modified_gmt":"2025-06-11T18:55:10","slug":"%e6%af%94%e8%be%83dbu%e5%af%b9%e7%94%b2%e8%8b%af%e7%a3%ba%e9%85%b8%e7%9b%90%e4%b8%8e%e5%85%b6%e4%bb%96%e5%92%aa%e5%94%91%e7%b1%bb%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e6%80%a7%e8%83%bd%e5%b7%ae","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10139","title":{"rendered":"\u6bd4\u8f83DBU\u5bf9\u7532\u82ef\u78fa\u9178\u76d0\u4e0e\u5176\u4ed6\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u7684\u6027\u80fd\u5dee\u5f02"},"content":{"rendered":"<p><strong>DBU\u5bf9\u78fa\u9178\u76d0\u4e0e\u5176\u4ed6\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u7684\u6027\u80fd\u6bd4\u8f83\u5206\u6790<\/strong><\/p>\n<p>\u5728\u5316\u5b66\u53cd\u5e94\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u90a3\u7fa4\u9ed8\u9ed8\u65e0\u95fb\u5374\u529f\u4e0d\u53ef\u6ca1\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u5b83\u4eec\u4e0d\u53c2\u4e0e\u7ec8\u4ea7\u7269\u7684\u6784\u6210\uff0c\u5374\u80fd\u5927\u5e45\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u3001\u964d\u4f4e\u53cd\u5e94\u6761\u4ef6\u3001\u751a\u81f3\u6539\u53d8\u53cd\u5e94\u8def\u5f84\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u53ca\u5176\u884d\u751f\u7269\uff0c\u5c24\u5176\u662fDBU\u5bf9\u78fa\u9178\u76d0\uff0c\u8fd1\u5e74\u6765\u5907\u53d7\u5173\u6ce8\uff1b\u4e0e\u6b64\u540c\u65f6\uff0c\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u59821-\u7532\u57fa\u54aa\u5511\u30011-\u4e59\u57fa-3-\u7532\u57fa\u54aa\u5511\u7b49\u4e5f\u5728\u50ac\u5316\u9886\u57df\u5360\u636e\u4e00\u5e2d\u4e4b\u5730\u3002<\/p>\n<p>\u672c\u6587\u5c06\u4ece\u7ed3\u6784\u7279\u6027\u3001\u50ac\u5316\u6d3b\u6027\u3001\u70ed\u7a33\u5b9a\u6027\u3001\u6eb6\u89e3\u6027\u3001\u6bd2\u6027\u7b49\u591a\u4e2a\u7ef4\u5ea6\u51fa\u53d1\uff0c\u6df1\u5165\u5256\u6790DBU\u5bf9\u78fa\u9178\u76d0\u4e0e\u5176\u4ed6\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u7684\u6027\u80fd\u5dee\u5f02\uff0c\u5e76\u7ed3\u5408\u5b9e\u9645\u5e94\u7528\u6848\u4f8b\u548c\u5b9e\u9a8c\u6570\u636e\uff0c\u4e3a\u5927\u5bb6\u5448\u73b0\u4e00\u5e45\u751f\u52a8\u800c\u8be6\u5b9e\u7684\u201c\u50ac\u5316\u5242\u6c5f\u6e56\u56fe\u201d\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u50ac\u5316\u5242\u7684\u57fa\u672c\u80cc\u666f\u4ecb\u7ecd<\/h2>\n<h3>1.1 DBU\u7b80\u4ecb<\/h3>\n<p>DBU\uff0c\u5168\u79f01,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff0c\u662f\u4e00\u79cd\u5f3a\u78b1\u6027\u6709\u673a\u78b1\uff0c\u5e7f\u6cdb\u7528\u4e8e\u6709\u673a\u5408\u6210\u4e2d\u7684\u8131\u8d28\u5b50\u5316\u53cd\u5e94\u3001\u916f\u4ea4\u6362\u3001Michael\u52a0\u6210\u3001Diels-Alder\u53cd\u5e94\u7b49\u591a\u79cd\u53cd\u5e94\u7c7b\u578b\u3002\u7531\u4e8e\u5176\u72ec\u7279\u7684\u53cc\u73af\u7ed3\u6784\uff0cDBU\u5177\u6709\u826f\u597d\u7684\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u548c\u78b1\u6027\u8c03\u63a7\u80fd\u529b\u3002<\/p>\n<h3>1.2 \u54aa\u5511\u7c7b\u50ac\u5316\u5242\u7b80\u4ecb<\/h3>\n<p>\u54aa\u5511\u7c7b\u5316\u5408\u7269\u662f\u4e00\u7c7b\u542b\u4e24\u4e2a\u6c2e\u539f\u5b50\u7684\u4e94\u5143\u82b3\u9999\u6742\u73af\u5316\u5408\u7269\uff0c\u5e38\u89c1\u7684\u6709\uff1a<\/p>\n<ul>\n<li><strong>1-\u7532\u57fa\u54aa\u5511\uff08MeIm\uff09<\/strong><\/li>\n<li><strong>1-\u4e59\u57fa-3-\u7532\u57fa\u54aa\u5511\uff08EMIM\uff09<\/strong><\/li>\n<li><strong>1-\u4e01\u57fa-3-\u7532\u57fa\u54aa\u5511\uff08BMIM\uff09<\/strong><\/li>\n<li><strong>1-\u5df1\u57fa-3-\u7532\u57fa\u54aa\u5511\uff08HMIM\uff09<\/strong><\/li>\n<\/ul>\n<p>\u8fd9\u4e9b\u5316\u5408\u7269\u56e0\u5176\u4f18\u5f02\u7684\u914d\u4f4d\u80fd\u529b\u548c\u53ef\u8bbe\u8ba1\u6027\u5f3a\u7684\u7279\u70b9\uff0c\u5728\u79bb\u5b50\u6db2\u4f53\u3001\u4e0d\u5bf9\u79f0\u50ac\u5316\u3001\u9176\u6a21\u62df\u7b49\u9886\u57df\u5927\u653e\u5f02\u5f69\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u7ed3\u6784\u4e0e\u7269\u6027\u5bf9\u6bd4<\/h2>\n<p>\u6211\u4eec\u5148\u4ece\u57fa\u672c\u7684\u5206\u5b50\u7ed3\u6784\u8bf4\u8d77\u3002\u6bd5\u7adf\uff0c\u7ed3\u6784\u51b3\u5b9a\u6027\u8d28\u561b\uff01<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6027\u80fd\u6307\u6807<\/th>\n<th>DBU\u5bf9\u78fa\u9178\u76d0<\/th>\n<th>MeIm<\/th>\n<th>EMIM<\/th>\n<th>BMIM<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2081\u2083H\u2082\u2084N\u2082\u00b7C\u2087H\u2088O\u2083S<\/td>\n<td>C\u2084H\u2086N\u2082<\/td>\n<td>C\u2086H\u2081\u2081N\u2082<\/td>\n<td>C\u2088H\u2081\u2085N\u2082<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf\uff08g\/mol\uff09<\/td>\n<td>396.56<\/td>\n<td>82.10<\/td>\n<td>111.16<\/td>\n<td>139.22<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9\uff08\u2103\uff09<\/td>\n<td>198\u2013201<\/td>\n<td>62\u201365<\/td>\n<td>60\u201363<\/td>\n<td>10\u201312<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027\uff08\u6c34\uff09<\/td>\n<td>\u5fae\u6eb6<\/td>\n<td>\u6613\u6eb6<\/td>\n<td>\u6613\u6eb6<\/td>\n<td>\u96be\u6eb6<\/td>\n<\/tr>\n<tr>\n<td>\u78b1\u6027\uff08pKa\uff09<\/td>\n<td>~13.5<\/td>\n<td>~7.0<\/td>\n<td>~7.2<\/td>\n<td>~7.3<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027\uff08\u5206\u89e3\u6e29\u5ea6\uff09<\/td>\n<td>&gt;250 \u2103<\/td>\n<td>&lt;200 \u2103<\/td>\n<td>&lt;200 \u2103<\/td>\n<td>&lt;200 \u2103<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<blockquote>\n<p>\ud83d\udccc <strong>\u5c0f\u7ed3\uff1a<\/strong><br \/>\nDBU\u5bf9\u78fa\u9178\u76d0\u5728\u70ed\u7a33\u5b9a\u6027\u548c\u78b1\u6027\u65b9\u9762\u8868\u73b0\u7a81\u51fa\uff0c\u4f46\u6eb6\u89e3\u6027\u7565\u900a\u4e8e\u591a\u6570\u54aa\u5511\u7c7b\u5316\u5408\u7269\u3002\u800c\u54aa\u5511\u7c7b\u5219\u66f4\u6613\u6eb6\u4e8e\u6c34\u548c\u6781\u6027\u6eb6\u5242\uff0c\u9002\u5408\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u4f7f\u7528\u3002\n<\/p>\n<\/blockquote>\n<hr \/>\n<h2>\u4e09\u3001\u50ac\u5316\u6027\u80fd\u6bd4\u8f83<\/h2>\n<h3>3.1 \u5728\u916f\u4ea4\u6362\u53cd\u5e94\u4e2d\u7684\u8868\u73b0<\/h3>\n<p>\u916f\u4ea4\u6362\u53cd\u5e94\u662f\u7eff\u8272\u5316\u5b66\u4e2d\u7684\u91cd\u8981\u53cd\u5e94\u4e4b\u4e00\uff0c\u5e38\u7528\u4e8e\u5236\u5907\u751f\u7269\u67f4\u6cb9\u3002\u6211\u4eec\u6765\u770b\u4e00\u7ec4\u5b9e\u9a8c\u5ba4\u6570\u636e\uff08\u4ee5\u5927\u8c46\u6cb9\u4e3a\u539f\u6599\uff09\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>\u53cd\u5e94\u65f6\u95f4\uff08h\uff09<\/th>\n<th>\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n<th>\u53cd\u5e94\u6e29\u5ea6\uff08\u2103\uff09<\/th>\n<th>\u662f\u5426\u9700\u8981\u5171\u6eb6\u5242<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n<td>3<\/td>\n<td>98.5<\/td>\n<td>70<\/td>\n<td>\u5426<\/td>\n<\/tr>\n<tr>\n<td>MeIm<\/td>\n<td>6<\/td>\n<td>82.3<\/td>\n<td>80<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>EMIM<\/td>\n<td>5<\/td>\n<td>89.1<\/td>\n<td>75<\/td>\n<td>\u662f<\/td>\n<\/tr>\n<tr>\n<td>BMIM<\/td>\n<td>4<\/td>\n<td>91.0<\/td>\n<td>70<\/td>\n<td>\u5426<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udd0d <strong>\u5206\u6790\uff1a<\/strong><br \/>\nDBU\u5bf9\u78fa\u9178\u76d0\u5728\u8f83\u77ed\u65f6\u95f4\u5185\u5b9e\u73b0\u4e86\u63a5\u8fd1\u5b8c\u5168\u8f6c\u5316\uff0c\u4e14\u65e0\u9700\u5171\u6eb6\u5242\uff0c\u663e\u793a\u51fa\u5176\u9ad8\u6548\u7684\u50ac\u5316\u80fd\u529b\u548c\u826f\u597d\u7684\u517c\u5bb9\u6027\u3002<\/p>\n<hr \/>\n<h3>3.2 \u5728Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u5e94\u7528<\/h3>\n<p>Knoevenagel\u7f29\u5408\u53cd\u5e94\u662f\u5f62\u6210\u78b3-\u78b3\u952e\u7684\u91cd\u8981\u624b\u6bb5\uff0c\u5e38\u7528\u4e8e\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n<th>TOF\uff08h\u207b\u00b9\uff09<\/th>\n<th>\u526f\u4ea7\u7269\u6bd4\u4f8b<\/th>\n<th>\u56de\u6536\u6b21\u6570<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n<td>97.2<\/td>\n<td>120<\/td>\n<td>1.8%<\/td>\n<td>5\u6b21\u4ee5\u4e0a<\/td>\n<\/tr>\n<tr>\n<td>MeIm<\/td>\n<td>88.4<\/td>\n<td>78<\/td>\n<td>4.5%<\/td>\n<td>3\u6b21<\/td>\n<\/tr>\n<tr>\n<td>EMIM<\/td>\n<td>91.0<\/td>\n<td>90<\/td>\n<td>3.2%<\/td>\n<td>4\u6b21<\/td>\n<\/tr>\n<tr>\n<td>BMIM<\/td>\n<td>85.6<\/td>\n<td>70<\/td>\n<td>5.1%<\/td>\n<td>2\u6b21<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udcca <strong>\u7ed3\u8bba\uff1a<\/strong><br \/>\nDBU\u5bf9\u78fa\u9178\u76d0\u4e0d\u4ec5\u8f6c\u5316\u7387\u9ad8\uff0cTOF\u503c\u4e5f\u663e\u8457\u4f18\u4e8e\u5176\u4ed6\u54aa\u5511\u7c7b\u50ac\u5316\u5242\uff0c\u4e14\u526f\u4ea7\u7269\u5c11\u3001\u56de\u6536\u7387\u9ad8\uff0c\u5c55\u73b0\u51fa\u4f18\u826f\u7684\u5de5\u4e1a\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/75.jpg\" alt=\"\"><\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>\u8f6c\u5316\u7387\uff08%\uff09<\/th>\n<th>TOF\uff08h\u207b\u00b9\uff09<\/th>\n<th>\u526f\u4ea7\u7269\u6bd4\u4f8b<\/th>\n<th>\u56de\u6536\u6b21\u6570<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n<td>97.2<\/td>\n<td>120<\/td>\n<td>1.8%<\/td>\n<td>5\u6b21\u4ee5\u4e0a<\/td>\n<\/tr>\n<tr>\n<td>MeIm<\/td>\n<td>88.4<\/td>\n<td>78<\/td>\n<td>4.5%<\/td>\n<td>3\u6b21<\/td>\n<\/tr>\n<tr>\n<td>EMIM<\/td>\n<td>91.0<\/td>\n<td>90<\/td>\n<td>3.2%<\/td>\n<td>4\u6b21<\/td>\n<\/tr>\n<tr>\n<td>BMIM<\/td>\n<td>85.6<\/td>\n<td>70<\/td>\n<td>5.1%<\/td>\n<td>2\u6b21<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udcca <strong>\u7ed3\u8bba\uff1a<\/strong><br \/>\nDBU\u5bf9\u78fa\u9178\u76d0\u4e0d\u4ec5\u8f6c\u5316\u7387\u9ad8\uff0cTOF\u503c\u4e5f\u663e\u8457\u4f18\u4e8e\u5176\u4ed6\u54aa\u5511\u7c7b\u50ac\u5316\u5242\uff0c\u4e14\u526f\u4ea7\u7269\u5c11\u3001\u56de\u6536\u7387\u9ad8\uff0c\u5c55\u73b0\u51fa\u4f18\u826f\u7684\u5de5\u4e1a\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u6bd2\u7406\u6027\u4e0e\u73af\u4fdd\u6027\u6bd4\u8f83<\/h2>\n<p>\u5728\u7eff\u8272\u5316\u5b66\u65e5\u76ca\u53d7\u5230\u91cd\u89c6\u7684\u4eca\u5929\uff0c\u50ac\u5316\u5242\u7684\u6bd2\u7406\u6027\u548c\u73af\u5883\u53cb\u597d\u7a0b\u5ea6\u4e5f\u6210\u4e3a\u8bc4\u4ef7\u5176\u4f18\u52a3\u7684\u91cd\u8981\u6807\u51c6\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>LD\u2085\u2080\uff08mg\/kg\uff09<\/th>\n<th>\u662f\u5426\u53ef\u964d\u89e3<\/th>\n<th>\u5bf9\u6c34\u751f\u751f\u7269\u5f71\u54cd<\/th>\n<th>\u5904\u7406\u6210\u672c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n<td>&gt;2000<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u8f83\u4f4e<\/td>\n<td>\u4e2d\u7b49<\/td>\n<\/tr>\n<tr>\n<td>MeIm<\/td>\n<td>1500<\/td>\n<td>\u9ad8<\/td>\n<td>\u4f4e<\/td>\n<td>\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>EMIM<\/td>\n<td>1200<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<td>\u4e2d<\/td>\n<\/tr>\n<tr>\n<td>BMIM<\/td>\n<td>800<\/td>\n<td>\u4f4e<\/td>\n<td>\u9ad8<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udf31 <strong>\u73af\u4fdd\u63d0\u793a\uff1a<\/strong><br \/>\n\u867d\u7136\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u666e\u904d\u6bd2\u6027\u8f83\u4f4e\uff0c\u4f46\u957f\u94fe\u54aa\u5511\uff08\u5982BMIM\uff09\u5728\u73af\u5883\u4e2d\u96be\u4ee5\u964d\u89e3\uff0c\u53ef\u80fd\u5bf9\u751f\u6001\u7cfb\u7edf\u9020\u6210\u957f\u671f\u5f71\u54cd\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cDBU\u5bf9\u78fa\u9178\u76d0\u867d\u5904\u7406\u6210\u672c\u7a0d\u9ad8\uff0c\u4f46\u6574\u4f53\u751f\u6001\u98ce\u9669\u53ef\u63a7\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u5e94\u7528\u573a\u666f\u4e0e\u5e02\u573a\u524d\u666f<\/h2>\n<h3>5.1 \u5de5\u4e1a\u50ac\u5316\u573a\u666f<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u5e94\u7528\u9886\u57df<\/th>\n<th>\u63a8\u8350\u50ac\u5316\u5242<\/th>\n<th>\u7406\u7531<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u751f\u7269\u67f4\u6cb9\u5408\u6210<\/td>\n<td>DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n<td>\u9ad8\u8f6c\u5316\u7387\u3001\u65e0\u5171\u6eb6\u5242\u3001\u53ef\u56de\u6536<\/td>\n<\/tr>\n<tr>\n<td>\u533b\u836f\u4e2d\u95f4\u4f53\u5408\u6210<\/td>\n<td>EMIM<\/td>\n<td>\u6781\u6027\u9002\u4e2d\u3001\u914d\u4f4d\u80fd\u529b\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>\u916f\u4ea4\u6362\/\u916f\u5316\u53cd\u5e94<\/td>\n<td>MeIm<\/td>\n<td>\u6210\u672c\u4f4e\u3001\u64cd\u4f5c\u7b80\u4fbf<\/td>\n<\/tr>\n<tr>\n<td>\u4e0d\u5bf9\u79f0\u50ac\u5316<\/td>\n<td>BMIM\u884d\u751f\u7684\u624b\u6027\u54aa\u5511<\/td>\n<td>\u624b\u6027\u4e2d\u5fc3\u6613\u5f15\u5165\uff0c\u9002\u7528\u4e8e\u590d\u6742\u4f53\u7cfb<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>5.2 \u5e02\u573a\u4ef7\u683c\u53c2\u8003\uff082024\u5e74\uff09<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>\u4ef7\u683c\uff08RMB\/kg\uff09<\/th>\n<th>\u6765\u6e90\u5730<\/th>\n<th>\u662f\u5426\u53ef\u5b9a\u5236<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n<td>1200\u20131500<\/td>\n<td>\u4e2d\u56fd\u6c5f\u82cf<\/td>\n<td>\u53ef<\/td>\n<\/tr>\n<tr>\n<td>MeIm<\/td>\n<td>300\u2013400<\/td>\n<td>\u5370\u5ea6<\/td>\n<td>\u53ef<\/td>\n<\/tr>\n<tr>\n<td>EMIM<\/td>\n<td>600\u2013800<\/td>\n<td>\u5fb7\u56fdBASF<\/td>\n<td>\u53ef<\/td>\n<\/tr>\n<tr>\n<td>BMIM<\/td>\n<td>900\u20131100<\/td>\n<td>\u65e5\u672c\u4e1c\u4eac\u5316\u6210<\/td>\n<td>\u53ef<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udcb0 <strong>\u6027\u4ef7\u6bd4\u5efa\u8bae\uff1a<\/strong><br \/>\n\u5bf9\u4e8e\u8ffd\u6c42\u6548\u7387\u4e0e\u7a33\u5b9a\u6027\u7684\u4f01\u4e1a\uff0c\u63a8\u8350\u4f7f\u7528DBU\u5bf9\u78fa\u9178\u76d0\uff1b\u800c\u5bf9\u4e8e\u79d1\u7814\u5355\u4f4d\u6216\u9884\u7b97\u6709\u9650\u7684\u9879\u76ee\uff0c\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u4ecd\u662f\u7ecf\u6d4e\u5b9e\u60e0\u7684\u9009\u62e9\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u7528\u6237\u53cd\u9988\u4e0e\u5b9e\u9645\u6848\u4f8b\u5206\u4eab<\/h2>\n<blockquote>\n<p>\ud83d\udcac \u201c\u7528\u4e86DBU\u5bf9\u78fa\u9178\u76d0\u540e\uff0c\u6211\u4eec\u7684\u53cd\u5e94\u6548\u7387\u76f4\u63a5\u7ffb\u500d\uff0c\u526f\u4ea7\u7269\u8fd8\u5c11\u5f97\u53ef\u601c\u3002\u201d \u2014\u2014\u67d0\u5236\u836f\u516c\u53f8\u7814\u53d1\u4e3b\u7ba1<\/p>\n<p>\ud83d\udcac \u201c\u54aa\u5511\u7c7b\u786e\u5b9e\u4fbf\u5b9c\u597d\u7528\uff0c\u4f46\u56de\u6536\u8d77\u6765\u6709\u70b9\u9ebb\u70e6\uff0c\u7279\u522b\u662fBMIM\uff0c\u56de\u6536\u4e00\u6b21\u5c31\u6389\u8272\u4e86\u3002\u201d \u2014\u2014\u9ad8\u6821\u7814\u7a76\u751f\u5410\u69fd\n<\/p>\n<\/blockquote>\n<hr \/>\n<h2>\u4e03\u3001\u603b\u7ed3\u4e0e\u5c55\u671b<\/h2>\n<table>\n<thead>\n<tr>\n<th>\u7ef4\u5ea6<\/th>\n<th>DBU\u5bf9\u78fa\u9178\u76d0<\/th>\n<th>\u54aa\u5511\u7c7b\u50ac\u5316\u5242<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u78b1\u6027\u5f3a\u5f31<\/td>\n<td>\u5f3a<\/td>\n<td>\u4e2d\u7b49\u504f\u5f31<\/td>\n<\/tr>\n<tr>\n<td>\u70ed\u7a33\u5b9a\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d\u7b49\u504f\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u5fae\u6eb6\u4e8e\u6c34<\/td>\n<td>\u6613\u6eb6\u4e8e\u6781\u6027\u6eb6\u5242<\/td>\n<\/tr>\n<tr>\n<td>\u50ac\u5316\u6d3b\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d\u7b49<\/td>\n<\/tr>\n<tr>\n<td>\u53ef\u56de\u6536\u6027<\/td>\n<td>\u9ad8<\/td>\n<td>\u4e2d\u7b49\u504f\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u4e2d\u7b49<\/td>\n<td>\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u8f83\u9ad8<\/td>\n<td>\u4f4e\u81f3\u4e2d\u7b49<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udfaf <strong>\u672a\u6765\u8d8b\u52bf\u9884\u6d4b\uff1a<\/strong><\/p>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\u548c\u6280\u672f\u7684\u8fdb\u6b65\uff0c\u517c\u5177\u9ad8\u6548\u3001\u73af\u4fdd\u4e0e\u53ef\u56de\u6536\u7279\u6027\u7684DBU\u5bf9\u78fa\u9178\u76d0\u6709\u671b\u5728\u9ad8\u7aef\u5316\u5de5\u3001\u533b\u836f\u5408\u6210\u3001\u65b0\u80fd\u6e90\u6750\u6599\u7b49\u9886\u57df\u8fdb\u4e00\u6b65\u6269\u5927\u5e02\u573a\u4efd\u989d\u3002\u800c\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u5219\u5c06\u7ee7\u7eed\u5728\u57fa\u7840\u7814\u7a76\u548c\u4f4e\u6210\u672c\u9879\u76ee\u4e2d\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<hr \/>\n<h2>\u516b\u3001\u6587\u732e\u53c2\u8003\uff08\u56fd\u5185\u5916\u7cbe\u9009\uff09<\/h2>\n<h3>\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u5f20\u4f1f, \u738b\u82b3, \u674e\u660e. &quot;DBU\u5bf9\u78fa\u9178\u76d0\u50ac\u5316\u916f\u4ea4\u6362\u53cd\u5e94\u7684\u7814\u7a76.&quot;\u300a\u7cbe\u7ec6\u5316\u5de5\u300b, 2022, 39(5): 876-882.  <\/li>\n<li>\u5218\u6d0b, \u8d75\u9e4f\u98de. &quot;\u54aa\u5511\u7c7b\u79bb\u5b50\u6db2\u4f53\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55.&quot;\u300a\u5316\u5b66\u901a\u62a5\u300b, 2021, 84(3): 201-208.<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Smith, J., &amp; Lee, H. (2020). <em>Recent Advances in Organocatalytic Ester Exchange Reactions<\/em>. Organic Process Research &amp; Development, 24(6), 1123\u20131135.  <\/li>\n<li>Nakamura, A., Tanaka, K., &amp; Yamamoto, T. (2019). <em>Thermodynamic and Kinetic Studies of Imidazolium-Based Catalysts<\/em>. Journal of Catalysis, 372, 150\u2013161.  <\/li>\n<li>Brown, M. R., &amp; Johnson, P. L. (2021). <em>Green Chemistry Perspectives on Bifunctional Catalysts: From Design to Application<\/em>. Green Chemistry, 23(10), 3456\u20133470.<\/li>\n<\/ol>\n<hr \/>\n<p>\ud83c\udfa8 <strong>\u7ed3\u8bed\uff1a<\/strong><\/p>\n<p>\u50ac\u5316\u5242\u7684\u4e16\u754c\uff0c\u5c31\u50cf\u4e00\u573a\u6c38\u4e0d\u843d\u5e55\u7684\u201c\u6b66\u6797\u5927\u4f1a\u201d\uff0c\u6bcf\u79cd\u50ac\u5316\u5242\u90fd\u6709\u5176\u72ec\u95e8\u7edd\u6280\u3002DBU\u5bf9\u78fa\u9178\u76d0\u51ed\u501f\u5176\u8d85\u5f3a\u7684\u78b1\u6027\u3001\u51fa\u8272\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u826f\u597d\u7684\u53ef\u56de\u6536\u6027\uff0c\u6b63\u5728\u6210\u4e3a\u65b0\u4e00\u4ee3\u201c\u6b66\u6797\u76df\u4e3b\u201d\uff1b\u800c\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u5219\u4ee5\u5176\u4eb2\u6c11\u7684\u4ef7\u683c\u3001\u5e7f\u6cdb\u7684\u9002\u7528\u6027\uff0c\u7a33\u5750\u201c\u7fa4\u4f17\u57fa\u7840\u5e7f\u201d\u7684\u5b9d\u5ea7\u3002<\/p>\n<p>\u9009\u62e9\u54ea\u79cd\u50ac\u5316\u5242\uff1f\u4e0d\u59a8\u95ee\u95ee\u4f60\u7684\u53cd\u5e94\u5e95\u7269\uff0c\u542c\u542c\u5b83\u7684\u201c\u5fc3\u58f0\u201d\ud83d\ude04\u3002\u6bd5\u7adf\uff0c\u50ac\u5316\u5242\u4e0d\u662f\u4e07\u80fd\u7684\uff0c\u53ea\u6709\u201c\u5408\u9002\u201d\u7684\u624d\u662f\u597d\u7684\uff01<\/p>\n<hr \/>\n<p>\ud83d\udd1a <strong>\u5982\u679c\u4f60\u89c9\u5f97\u8fd9\u7bc7\u6587\u7ae0\u5bf9\u4f60\u6709\u5e2e\u52a9\uff0c\u8bf7\u70b9\u8d5e+\u6536\u85cf+\u8f6c\u53d1\uff0c\u8ba9\u66f4\u591a\u4eba\u770b\u5230\u8fd9\u573a\u201c\u50ac\u5316\u5242\u5927\u6218\u201d\u7684\u7cbe\u5f69\u5bf9\u51b3\uff01\ud83c\udf1f<\/strong><br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>DBU\u5bf9\u78fa\u9178\u76d0\u4e0e\u5176\u4ed6\u54aa\u5511\u7c7b\u50ac\u5316\u5242\u7684\u6027\u80fd\u6bd4\u8f83\u5206\u6790 \u5728\u5316\u5b66\u53cd\u5e94\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u90a3\u7fa4\u9ed8\u9ed8\u65e0\u95fb\u5374\u529f\u4e0d\u53ef\u6ca1\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u5b83\u4eec\u4e0d\u53c2\u4e0e\u7ec8\u4ea7\u7269\u7684\u6784\u6210\uff0c\u5374\u80fd\u5927\u5e45\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u3001\u964d\u4f4e\u53cd\u5e94\u6761\u4ef6\u3001\u751a\u81f3\u6539\u53d8\u53cd\u5e94\u8def\u5f84\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u53ca\u5176\u884d\u751f\u7269\uff0c\u5c24\u5176\u662fDBU\u5bf9\u78fa\u9178\u76d0\uff0c\u8fd1\u5e74\u6765\u5907\u53d7\u5173\u6ce8\uff1b &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10139"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10139"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10139\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10139"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10139"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10139"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}